A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose

Ville Tuppurainen; Jani Kangas; Juha Ahola; Juha Tanskanen; Atte Aho; Henrik Grénman; Dmitry Yu Murzin; Tapio Salmi

doi:10.1016/B978-0-12-823377-1.50290-1

A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose

Ville Tuppurainen, Jani Kangas, Juha Ahola, Juha Tanskanen, Atte Aho, Henrik Grénman, Dmitry Yu Murzin, Tapio Salmi

Forskningsoutput: Kapitel i bok/konferenshandling › Konferensbidrag › Vetenskaplig › Peer review

Sammanfattning

A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H₂. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H₂, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H₂ and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.

Originalspråk	Engelska
Titel på värdpublikation	Computer Aided Chemical Engineering
Förlag	Elsevier B.V.
Sidor	1735-1740
Antal sidor	6
ISBN (elektroniskt)	978-0-12-823378-8
ISBN (tryckt)	978-0-12-823377-1
DOI	https://doi.org/10.1016/B978-0-12-823377-1.50290-1
Status	Publicerad - jan. 2020
MoE-publikationstyp	A4 Artikel i en konferenspublikation
Evenemang	30th European Symposium on Computer Aided Process Engineering - Milan, Italien Varaktighet: 24 maj 2020 → 27 maj 2020 Konferensnummer: 30

Publikationsserier

Namn	Computer Aided Chemical Engineering
Volym	48
ISSN (tryckt)	1570-7946

Konferens

Konferens	30th European Symposium on Computer Aided Process Engineering
Förkortad titel	ESCAPE)
Land/Territorium	Italien
Ort	Milan
Period	24/05/20 → 27/05/20

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10.1016/B978-0-12-823377-1.50290-1

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title = "A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose",

abstract = "A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H2. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H2, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H2 and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.",

keywords = "Aqueous Phase Reforming, Bio-based Hydrogen, Hemicellulose Extraction",

author = "Ville Tuppurainen and Jani Kangas and Juha Ahola and Juha Tanskanen and Atte Aho and Henrik Gr{\'e}nman and Murzin, {Dmitry Yu} and Tapio Salmi",

note = "Funding Information: The authors are grateful for the financial support from Business Finland (Biohydrogen from wood hemicellulose hydrolysate, HemiH2, 2017-2019). Publisher Copyright: {\textcopyright} 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.; 30th European Symposium on Computer Aided Process Engineering, ESCAPE) ; Conference date: 24-05-2020 Through 27-05-2020",

year = "2020",

month = jan,

doi = "10.1016/B978-0-12-823377-1.50290-1",

language = "English",

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series = "Computer Aided Chemical Engineering",

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booktitle = "Computer Aided Chemical Engineering",

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Tuppurainen, V, Kangas, J, Ahola, J, Tanskanen, J, Aho, A , Grénman, H , Murzin, DY & Salmi, T 2020, A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose. i Computer Aided Chemical Engineering. Computer Aided Chemical Engineering, vol. 48, Elsevier B.V., s. 1735-1740, 30th European Symposium on Computer Aided Process Engineering, Milan, Italien, 24/05/20. https://doi.org/10.1016/B978-0-12-823377-1.50290-1

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AU - Tuppurainen, Ville

AU - Kangas, Jani

AU - Ahola, Juha

AU - Tanskanen, Juha

AU - Aho, Atte

AU - Grénman, Henrik

AU - Murzin, Dmitry Yu

AU - Salmi, Tapio

N1 - Conference code: 30

PY - 2020/1

Y1 - 2020/1

N2 - A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H2. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H2, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H2 and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.

AB - A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H2. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H2, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H2 and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.

KW - Aqueous Phase Reforming

KW - Bio-based Hydrogen

KW - Hemicellulose Extraction

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A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose

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