A short semi-synthesis and complete NMR-spectroscopic characterization of the naturally occurring lignan glycoside matairesinol 4,4 '-di-O-beta-D-diglucoside

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    Sammanfattning

    A convenient semi-synthesis of (8R,8'R)-matairesinol 4,4'-di-O-beta-D-glucopyranoside (MDG), found in the stems of Trachelospermum asiaticum var. intermedium, is described starting from the readily available starting materials D-glucose and hydroxymatairesinol. By this approach the synthesis of MDG can be accomplished in six steps with an overall yield of 28%. In addition, the first complete NMR-spectroscopic characterization of MDG was accomplished by the combination of standard NMR techniques and spectral simulations performed with the PERCH NMR simulation software. (C) 2010 Elsevier Ltd. All rights reserved.
    OriginalspråkOdefinierat/okänt
    Sidor (från-till)1963–1967
    Antal sidor5
    TidskriftCarbohydrate Research
    Volym345
    Utgåva13
    DOI
    StatusPublicerad - 2010
    MoE-publikationstypA1 Tidskriftsartikel-refererad

    Nyckelord

    • Lignan glycoside
    • NMR spectroscopy
    • Semi-synthesis
    • Trachelospermum asiaticum var. intermedium

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