[1,5]-Silatropic shifts in disilyl substituted indenes: an NMR spectroscopic and computational study

Satu Silver; Ville Nieminen; Reko Leino

doi:10.1016/j.tet.2006.07.040

[1,5]-Silatropic shifts in disilyl substituted indenes: an NMR spectroscopic and computational study

Satu Silver
, Ville Nieminen
, Reko Leino

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

4 Citeringar (Scopus)

Sammanfattning

The equilibrium profiles for [1,5]-silatropic shifts in a series of 1,3-/1,1-disilyl substituted indenes were studied by NMR and computational methods based on density functional theory. Both methods indicate higher activation parameters for the [1,5]-shifts than observed in monosilyl substituted indene analogues.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	9417–9422
Antal sidor	6
Tidskrift	Tetrahedron
Volym	62
Nummer	40
DOI	https://doi.org/10.1016/j.tet.2006.07.040
Status	Publicerad - 2006
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Åtkomst av dokument

10.1016/j.tet.2006.07.040

http://www.sciencedirect.com/science/article/pii/S0040402006011549

Citera det här

@article{79c1e6bd85f04ece93ea2fa8b84016b4,

title = "[1,5]-Silatropic shifts in disilyl substituted indenes: an NMR spectroscopic and computational study",

abstract = "The equilibrium profiles for [1,5]-silatropic shifts in a series of 1,3-/1,1-disilyl substituted indenes were studied by NMR and computational methods based on density functional theory. Both methods indicate higher activation parameters for the [1,5]-shifts than observed in monosilyl substituted indene analogues.",

author = "Satu Silver and Ville Nieminen and Reko Leino",

note = "iok Satu Silver \& Ville Nieminen are also affiliated wit {\AA}AU",

year = "2006",

doi = "10.1016/j.tet.2006.07.040",

language = "Odefinierat/ok{\"a}nt",

volume = "62",

pages = "9417–9422",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier",

number = "40",

}

TY - JOUR

T1 - [1,5]-Silatropic shifts in disilyl substituted indenes: an NMR spectroscopic and computational study

AU - Silver, Satu

AU - Nieminen, Ville

AU - Leino, Reko

N1 - iok Satu Silver & Ville Nieminen are also affiliated wit ÅAU

PY - 2006

Y1 - 2006

N2 - The equilibrium profiles for [1,5]-silatropic shifts in a series of 1,3-/1,1-disilyl substituted indenes were studied by NMR and computational methods based on density functional theory. Both methods indicate higher activation parameters for the [1,5]-shifts than observed in monosilyl substituted indene analogues.

AB - The equilibrium profiles for [1,5]-silatropic shifts in a series of 1,3-/1,1-disilyl substituted indenes were studied by NMR and computational methods based on density functional theory. Both methods indicate higher activation parameters for the [1,5]-shifts than observed in monosilyl substituted indene analogues.

U2 - 10.1016/j.tet.2006.07.040

DO - 10.1016/j.tet.2006.07.040

M3 - Artikel

SN - 0040-4020

VL - 62

SP - 9417

EP - 9422

JO - Tetrahedron

JF - Tetrahedron

IS - 40

ER -