[1,5]-Silatropic shifts in disilyl substituted indenes: an NMR spectroscopic and computational study

Satu Silver, Ville Nieminen, Reko Leino

    Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

    4 Citeringar (Scopus)

    Sammanfattning

    The equilibrium profiles for [1,5]-silatropic shifts in a series of 1,3-/1,1-disilyl substituted indenes were studied by NMR and computational methods based on density functional theory. Both methods indicate higher activation parameters for the [1,5]-shifts than observed in monosilyl substituted indene analogues.
    OriginalspråkOdefinierat/okänt
    Sidor (från-till)9417–9422
    Antal sidor6
    TidskriftTetrahedron
    Volym62
    Utgåva40
    DOI
    StatusPublicerad - 2006
    MoE-publikationstypA1 Tidskriftsartikel-refererad

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