Zeolite catalyst based micro-reactors: Enhancement of zeolite coating interaction via pretreatment of micro-reactor elements

N. Kumar*, S. Schmidt, B. Zhang, K. Eränen, D. Yu Murzin, T. Salmi

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Konferenssiin myötävaikuttaminenTutkielmavertaisarvioitu

Abstrakti

Acidic and metal modified micro-porous zeolite catalysts are used in commercial processes in petroleum industry for petro-chemicals production, fuel components, and abatement of emissions from exhaust gas. Synthesis of acid and metal modified zeolite catalysts based micro-reactors was carried out, with special emphasis on the enhancement of interaction of zeolite coating via pretreatment of micro-reactor elements. The micro-reactor elements were pretreated at 923, 1023 and 1123 K, and the highest surface roughness obtained was 0.476 μm for 1123 K and the lowest surface roughness was 0.158 μm for the micro-reactor elements pretreated at 923 K. The micro-reactor elements pretreated with phosphoric acid and acetic acid showed a surface roughness of 0.157 μm. During the stability test on the adhesion of the zeolite coatings to the micro-reactor elements carried out using ultrasound irradiation and high flow of nitrogen, zeolite coating remained attached to the surface of micro-reactor elements. However, H-MCM-22 and H-ZSM-5 zeolite catalysts coated in the channels of pristine untreated micro-reactor element were removed during the ultrasound irradiation and high nitrogen flow treatment. This is an abstract of a paper presented at the CHISA 2012 - 20th International Congress of Chemical and Process Engineering and PRES 2012 - 15th Conference PRES (Prague, Czech Republic 8/25-29/2012).

AlkuperäiskieliEnglanti
TilaJulkaistu - 2012
OKM-julkaisutyyppiO2 Other
Tapahtuma20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012 - Prague, Czech Republic
Kesto: 25 elokuuta 201229 elokuuta 2012

Konferenssi

Konferenssi20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012
Maa/AlueCzech Republic
KaupunkiPrague
Ajanjakso25/08/1229/08/12

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