Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline

Heidi Maria Bernas; Yuliya S. Demidova; Atte Aho; Irina L. Simakova; Narendra Kumar; Yosra Laribi; Philippe Perrichon; Reko Leino; Dmitry Murzin

doi:10.1007/s10562-014-1474-3

Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline

Heidi Maria Bernas, Yuliya S. Demidova, Atte Aho, Irina L. Simakova, Narendra Kumar, Yosra Laribi, Philippe Perrichon, Reko Leino, Dmitry Murzin

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

2 Sitaatiot (Scopus)

Abstrakti

The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.

Alkuperäiskieli	Ei tiedossa
Sivut	955–963
Julkaisu	Catalysis Letters
Vuosikerta	145
Numero	3
DOI - pysyväislinkit	https://doi.org/10.1007/s10562-014-1474-3
Tila	Julkaistu - 2015
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1007/s10562-014-1474-3

http://download.springer.com/static/pdf/61/art%253A10.1007%252Fs10562-014-1474-3.pdf?originUrl=http%3A%2F%2Flink.springer.com%2Farticle%2F10.1007%2Fs10562-014-1474-3&token2=exp=1453817990~acl=%2Fstatic%2Fpdf%2F61%2Fart%25253A10.1007%25252Fs10562-014-1474-3.pdf%3ForiginUrl%3Dhttp%253A%252F%252Flink.springer.com%252Farticle%252F10.1007%252Fs10562-014-1474-3*~hmac=c0a78bb670debc515fd33958a3f2a74cb59c289fb797f22909cd77cbe1a2c1db

Viittausmuodot

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title = "Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline",

abstract = "The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.",

author = "Bernas, {Heidi Maria} and Demidova, {Yuliya S.} and Atte Aho and Simakova, {Irina L.} and Narendra Kumar and Yosra Laribi and Philippe Perrichon and Reko Leino and Dmitry Murzin",

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TY - JOUR

T1 - Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline

AU - Bernas, Heidi Maria

AU - Demidova, Yuliya S.

AU - Aho, Atte

AU - Simakova, Irina L.

AU - Kumar, Narendra

AU - Laribi, Yosra

AU - Perrichon, Philippe

AU - Leino, Reko

AU - Murzin, Dmitry

N1 - tk. iok

PY - 2015

Y1 - 2015

N2 - The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.

AB - The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.

U2 - 10.1007/s10562-014-1474-3

DO - 10.1007/s10562-014-1474-3

M3 - Artikel

SN - 1011-372X

VL - 145

SP - 955

EP - 963

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3

ER -