The impact of wollastonite and dolomite on chemical durability of matte fast-fired raw glazes

Thomas Kronberg; Leena Hupa

doi:10.1016/j.jeurceramsoc.2020.03.033

The impact of wollastonite and dolomite on chemical durability of matte fast-fired raw glazes

Thomas Kronberg^*
, Leena Hupa

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

15 Sitaatiot (Scopus)

Abstrakti

Controlled share of wollastonite and dolomite in the recipe was decisive for achieving raw glazes with a matte surface in a fast-firing process. The surface characteristics were studied for 25 experimental glazes containing 9–39 wt% wollastonite and 0–16 wt% dolomite. The glaze suspensions were applied on raw tiles and fired to 1215 °C in an industrial kiln. The chemical durability of the tiles was measured according to the standard ISO 10545-13. Further, the impact of exposure time on surface degradation was measured for 0.1 and 3 vol% HCl-solutions. The changes in the phase composition were studied with SEM/EDXA and XRD. The surface consisted of wollastonite and diopside, some residual quartz and corundum as well as amorphous phases. Wollastonite crystals severely decreased the durability while diopside crystals provided a durable matte surface. The results give guidelines for manufacturing matte and chemically durable fast-fired raw glazes.

Alkuperäiskieli	Englanti
Sivut	3327-3337
Sivumäärä	11
Julkaisu	Journal of the European Ceramic Society
Vuosikerta	40
Numero	8
DOI - pysyväislinkit	https://doi.org/10.1016/j.jeurceramsoc.2020.03.033
Tila	Julkaistu - 18 maalisk. 2020
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Rahoitus

Jaana Paananen and Linus Silvander are thanked for helping out with the experimental work. The financial support from the Åbo Akademi Johan Gadolin Process Chemistry Centre is acknowledged.

Pääsy asiakirjaan

10.1016/j.jeurceramsoc.2020.03.033Lisenssi: All rights reserved

Viittausmuodot

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title = "The impact of wollastonite and dolomite on chemical durability of matte fast-fired raw glazes",

abstract = "Controlled share of wollastonite and dolomite in the recipe was decisive for achieving raw glazes with a matte surface in a fast-firing process. The surface characteristics were studied for 25 experimental glazes containing 9–39 wt\% wollastonite and 0–16 wt\% dolomite. The glaze suspensions were applied on raw tiles and fired to 1215 °C in an industrial kiln. The chemical durability of the tiles was measured according to the standard ISO 10545-13. Further, the impact of exposure time on surface degradation was measured for 0.1 and 3 vol\% HCl-solutions. The changes in the phase composition were studied with SEM/EDXA and XRD. The surface consisted of wollastonite and diopside, some residual quartz and corundum as well as amorphous phases. Wollastonite crystals severely decreased the durability while diopside crystals provided a durable matte surface. The results give guidelines for manufacturing matte and chemically durable fast-fired raw glazes.",

keywords = "Chemical durability, Diopside, Glaze, Matte glaze, Surface properties, Wollastonite",

author = "Thomas Kronberg and Leena Hupa",

note = "Funding Information: Jaana Paananen and Linus Silvander are thanked for helping out with the experimental work. The financial support from the {\AA}bo Akademi Johan Gadolin Process Chemistry Centre is acknowledged. Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = mar,

day = "18",

doi = "10.1016/j.jeurceramsoc.2020.03.033",

language = "English",

volume = "40",

pages = "3327--3337",

journal = "Journal of the European Ceramic Society",

issn = "0955-2219",

publisher = "Elsevier",

number = "8",

}

TY - JOUR

T1 - The impact of wollastonite and dolomite on chemical durability of matte fast-fired raw glazes

AU - Kronberg, Thomas

AU - Hupa, Leena

N1 - Funding Information: Jaana Paananen and Linus Silvander are thanked for helping out with the experimental work. The financial support from the Åbo Akademi Johan Gadolin Process Chemistry Centre is acknowledged. Publisher Copyright: © 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/3/18

Y1 - 2020/3/18

N2 - Controlled share of wollastonite and dolomite in the recipe was decisive for achieving raw glazes with a matte surface in a fast-firing process. The surface characteristics were studied for 25 experimental glazes containing 9–39 wt% wollastonite and 0–16 wt% dolomite. The glaze suspensions were applied on raw tiles and fired to 1215 °C in an industrial kiln. The chemical durability of the tiles was measured according to the standard ISO 10545-13. Further, the impact of exposure time on surface degradation was measured for 0.1 and 3 vol% HCl-solutions. The changes in the phase composition were studied with SEM/EDXA and XRD. The surface consisted of wollastonite and diopside, some residual quartz and corundum as well as amorphous phases. Wollastonite crystals severely decreased the durability while diopside crystals provided a durable matte surface. The results give guidelines for manufacturing matte and chemically durable fast-fired raw glazes.

AB - Controlled share of wollastonite and dolomite in the recipe was decisive for achieving raw glazes with a matte surface in a fast-firing process. The surface characteristics were studied for 25 experimental glazes containing 9–39 wt% wollastonite and 0–16 wt% dolomite. The glaze suspensions were applied on raw tiles and fired to 1215 °C in an industrial kiln. The chemical durability of the tiles was measured according to the standard ISO 10545-13. Further, the impact of exposure time on surface degradation was measured for 0.1 and 3 vol% HCl-solutions. The changes in the phase composition were studied with SEM/EDXA and XRD. The surface consisted of wollastonite and diopside, some residual quartz and corundum as well as amorphous phases. Wollastonite crystals severely decreased the durability while diopside crystals provided a durable matte surface. The results give guidelines for manufacturing matte and chemically durable fast-fired raw glazes.

KW - Chemical durability

KW - Diopside

KW - Glaze

KW - Matte glaze

KW - Surface properties

KW - Wollastonite

U2 - 10.1016/j.jeurceramsoc.2020.03.033

DO - 10.1016/j.jeurceramsoc.2020.03.033

M3 - Article

AN - SCOPUS:85082014865

SN - 0955-2219

VL - 40

SP - 3327

EP - 3337

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 8

ER -

The impact of wollastonite and dolomite on chemical durability of matte fast-fired raw glazes

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