The effect of storage conditions on extraction efficiency and identification of extractives in wood-containing paper

Sylwia Bialczak, Stefan Willför, Anna Sundberg

    Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

    3 Sitaatiot (Scopus)

    Abstrakti

    TMP-based newsprint paper was submitted to accelerated ageing at 60 degrees C for up to 7 days. The papers were submitted to storage in an oven either by hanging freely, in closed vials in ambient air, or in closed vials flushed with nitrogen. The amount and composition of accessible extractives decreases significantly during ageing of samples hanging freely, as analysed by gas chromatography and size-exclusion chromatography. Samples in closed vials in ambient air and in nitrogen showed only a small decrease of analysed extractives during the time of ageing. After alkaline hydrolysis of the extracts, dioic acids were present in all samples, but for the samples treated in open air in largest amounts. Oxidation is an important but not an exclusive mechanism of alteration of the extractives. To significantly slow down oxidation and other alteration processes, simple enclosure of the paper samples in glass vials is enough.
    AlkuperäiskieliEi tiedossa
    Sivut541–546
    Sivumäärä6
    JulkaisuNordic Pulp and Paper Research Journal
    Vuosikerta28
    Numero4
    TilaJulkaistu - 2013
    OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

    Keywords

    • Chemical characterization
    • Extractives
    • GC
    • HPSEC
    • Paper ageing
    • Paper storage
    • TMP

    Viittausmuodot