Synthesis of dimethyl carbonate from methanol and carbon dioxide the effect of dehydration

V. Eta*, P. Mäki-Arvela, D. Y. Murzin, T. Salmi, J. P. Mikkola

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Konferenssiin myötävaikuttaminenTutkielmavertaisarvioitu

Abstrakti

The catalytic activity of zirconia in the synthesis of dimethyl carbonate (DMC) from methanol and CO2 was studied. The thermodynamic properties of the reaction were estimated at different temperatures and pressures. Kinetic tests were carried out to determine the maximum yield and selectivity for DMC at different conditions. The limitations imposed by thermodynamics could be relaxed by using a chemical water trap to bind water produced during the reaction between methanol and CO2 thereby shifting the reaction equilibrium towards higher DMC yields. The catalytic performance improved significantly in the presence of strong basic sites incorporated into zirconia. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montreal, Quebec, Canada 8/23-27/2009).

AlkuperäiskieliEnglanti
Sivut522bc
TilaJulkaistu - 2009
OKM-julkaisutyyppiO2 Other
Tapahtuma8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering - Montreal, QC, Canada
Kesto: 23 elokuuta 200927 elokuuta 2009

Konferenssi

Konferenssi8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
MaaCanada
KaupunkiMontreal, QC
Ajanjakso23/08/0927/08/09

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