Sustainable Ketalization of Glycerol with Ethyl Levulinate Catalyzed by the Iron(III)-Based Metal-Organic Framework MIL-88A

Massimo Melchiorre; Domenico Lentini; Maria Elena Cucciolito; Francesco Taddeo; Maryam Hmoudah; Martino Di Serio; Francesco Ruffo; Vincenzo Russo; Roberto Esposito

doi:10.3390/molecules27217229

Sustainable Ketalization of Glycerol with Ethyl Levulinate Catalyzed by the Iron(III)-Based Metal-Organic Framework MIL-88A

Massimo Melchiorre
, Domenico Lentini
, Maria Elena Cucciolito
, Francesco Taddeo
, Maryam Hmoudah
, Martino Di Serio
, Francesco Ruffo
, Vincenzo Russo^*
, Roberto Esposito^*

^*Tämän työn vastaava kirjoittaja

Teknillisen kemian ja reaktiotekniikan laboratorio

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

16 Sitaatiot (Scopus)

163 Lataukset (Pure)

Abstrakti

The catalytic properties of a simple iron-containing MOF based on fumaric acid, MIL-88A, were investigated in the ketalization of ethyl levulinate with glycerol. The corresponding product is a component of current interest as a renewable building block for many uses. Under the following conditions (solventless, 120 °C, stoichiometric ratio, 1% cat.), the reaction proceeds with good yields (85%), and the catalyst can be recovered and recycled without loss of activity, despite some changes in the crystalline lattice and morphology. Moreover, the residual iron content in the product is in the order of units of ppm (≤2), which demonstrates the robustness of the MOF under the reaction conditions.

Alkuperäiskieli	Englanti
Artikkeli	7229
Julkaisu	Molecules
Vuosikerta	27
Numero	21
DOI - pysyväislinkit	https://doi.org/10.3390/molecules27217229
Tila	Julkaistu - marrask. 2022
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Rahoitus

The authors wish to thank Giuseppe Campanile and Rocco Di Girolamo for their help with the experimental setup and the European Union (FSE, PON Ricerca e Innovazione 2014-2020, Azione I.1 “Dottorati Innovativi con Caratterizzazione Industriale”) for funding the Ph.D. grant of F.T. R.E. thanks the European Union and MIUR for funding through PON-AIM project code E61G19000090002 and proposal code AIM1829571-1. The authors are grateful to the Italian Ministero dell’Istruzione dell’Università e della Ricerca for the financial support provided through the LEVANTE project “LEvulinic acid Valorization through Advanced Novel Technologies”, Progetti di Ricerca di Rilevante Interesse Nazionale Bando 2020, Prot. 2020CZCJN7.

Pääsy asiakirjaan

10.3390/molecules27217229

molecules-27-07229Lopullinen julkaistu versio, 3,63 MBLisenssi: CC BY

https://urn.fi/URN:NBN:fi-fe2023022228191

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@article{62baad00afcb4580b37544c38335fd7b,

title = "Sustainable Ketalization of Glycerol with Ethyl Levulinate Catalyzed by the Iron(III)-Based Metal-Organic Framework MIL-88A",

abstract = "The catalytic properties of a simple iron-containing MOF based on fumaric acid, MIL-88A, were investigated in the ketalization of ethyl levulinate with glycerol. The corresponding product is a component of current interest as a renewable building block for many uses. Under the following conditions (solventless, 120 °C, stoichiometric ratio, 1\% cat.), the reaction proceeds with good yields (85\%), and the catalyst can be recovered and recycled without loss of activity, despite some changes in the crystalline lattice and morphology. Moreover, the residual iron content in the product is in the order of units of ppm (≤2), which demonstrates the robustness of the MOF under the reaction conditions.",

keywords = "ethyl levulinate, glycerol, heterogeneous catalysis, ketalization, MOF",

author = "Massimo Melchiorre and Domenico Lentini and Cucciolito, \{Maria Elena\} and Francesco Taddeo and Maryam Hmoudah and \{Di Serio\}, Martino and Francesco Ruffo and Vincenzo Russo and Roberto Esposito",

note = "Funding Information: The authors wish to thank Giuseppe Campanile and Rocco Di Girolamo for their help with the experimental setup and the European Union (FSE, PON Ricerca e Innovazione 2014-2020, Azione I.1 {\textquotedblleft}Dottorati Innovativi con Caratterizzazione Industriale{\textquotedblright}) for funding the Ph.D. grant of F.T. R.E. thanks the European Union and MIUR for funding through PON-AIM project code E61G19000090002 and proposal code AIM1829571-1. The authors are grateful to the Italian Ministero dell{\textquoteright}Istruzione dell{\textquoteright}Universit{\`a} e della Ricerca for the financial support provided through the LEVANTE project {\textquotedblleft}LEvulinic acid Valorization through Advanced Novel Technologies{\textquotedblright}, Progetti di Ricerca di Rilevante Interesse Nazionale Bando 2020, Prot. 2020CZCJN7. Publisher Copyright: {\textcopyright} 2022 by the authors.",

year = "2022",

month = nov,

doi = "10.3390/molecules27217229",

language = "English",

volume = "27",

journal = "Molecules",

issn = "1420-3049",

publisher = "MDPI",

number = "21",

}

TY - JOUR

T1 - Sustainable Ketalization of Glycerol with Ethyl Levulinate Catalyzed by the Iron(III)-Based Metal-Organic Framework MIL-88A

AU - Melchiorre, Massimo

AU - Lentini, Domenico

AU - Cucciolito, Maria Elena

AU - Taddeo, Francesco

AU - Hmoudah, Maryam

AU - Di Serio, Martino

AU - Ruffo, Francesco

AU - Russo, Vincenzo

AU - Esposito, Roberto

N1 - Funding Information: The authors wish to thank Giuseppe Campanile and Rocco Di Girolamo for their help with the experimental setup and the European Union (FSE, PON Ricerca e Innovazione 2014-2020, Azione I.1 “Dottorati Innovativi con Caratterizzazione Industriale”) for funding the Ph.D. grant of F.T. R.E. thanks the European Union and MIUR for funding through PON-AIM project code E61G19000090002 and proposal code AIM1829571-1. The authors are grateful to the Italian Ministero dell’Istruzione dell’Università e della Ricerca for the financial support provided through the LEVANTE project “LEvulinic acid Valorization through Advanced Novel Technologies”, Progetti di Ricerca di Rilevante Interesse Nazionale Bando 2020, Prot. 2020CZCJN7. Publisher Copyright: © 2022 by the authors.

PY - 2022/11

Y1 - 2022/11

N2 - The catalytic properties of a simple iron-containing MOF based on fumaric acid, MIL-88A, were investigated in the ketalization of ethyl levulinate with glycerol. The corresponding product is a component of current interest as a renewable building block for many uses. Under the following conditions (solventless, 120 °C, stoichiometric ratio, 1% cat.), the reaction proceeds with good yields (85%), and the catalyst can be recovered and recycled without loss of activity, despite some changes in the crystalline lattice and morphology. Moreover, the residual iron content in the product is in the order of units of ppm (≤2), which demonstrates the robustness of the MOF under the reaction conditions.

AB - The catalytic properties of a simple iron-containing MOF based on fumaric acid, MIL-88A, were investigated in the ketalization of ethyl levulinate with glycerol. The corresponding product is a component of current interest as a renewable building block for many uses. Under the following conditions (solventless, 120 °C, stoichiometric ratio, 1% cat.), the reaction proceeds with good yields (85%), and the catalyst can be recovered and recycled without loss of activity, despite some changes in the crystalline lattice and morphology. Moreover, the residual iron content in the product is in the order of units of ppm (≤2), which demonstrates the robustness of the MOF under the reaction conditions.

KW - ethyl levulinate

KW - glycerol

KW - heterogeneous catalysis

KW - ketalization

KW - MOF

UR - https://www.scopus.com/pages/publications/85141616368

U2 - 10.3390/molecules27217229

DO - 10.3390/molecules27217229

M3 - Article

C2 - 36364056

AN - SCOPUS:85141616368

SN - 1420-3049

VL - 27

JO - Molecules

JF - Molecules

IS - 21

M1 - 7229

ER -

Sustainable Ketalization of Glycerol with Ethyl Levulinate Catalyzed by the Iron(III)-Based Metal-Organic Framework MIL-88A

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