Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents

Marek Kosmulski; Piotr Próchniak; Jarl B. Rosenholm

doi:10.1021/la902659w

Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents

Marek Kosmulski
, Piotr Próchniak
, Jarl B. Rosenholm

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

11 Sitaatiot (Scopus)

Abstrakti

The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. © 2009 American Chemical Society.

Alkuperäiskieli	Englanti
Sivut	1904-1909
Sivumäärä	6
Julkaisu	Langmuir
Vuosikerta	26
Numero	3
DOI - pysyväislinkit	https://doi.org/10.1021/la902659w
Tila	Julkaistu - helmik. 2010
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1021/la902659w

Muut tiedostot ja linkit

https://www.mendeley.com/catalogue/079f87bf-af44-3f57-8db0-9f73aaf45011/

Viittausmuodot

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title = "Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents",

abstract = "The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. {\textcopyright} 2009 American Chemical Society.",

author = "Marek Kosmulski and Piotr Pr{\'o}chniak and Rosenholm, \{Jarl B.\}",

year = "2010",

month = feb,

doi = "10.1021/la902659w",

language = "English",

volume = "26",

pages = "1904--1909",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American chemical society",

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TY - JOUR

T1 - Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents

AU - Kosmulski, Marek

AU - Próchniak, Piotr

AU - Rosenholm, Jarl B.

PY - 2010/2

Y1 - 2010/2

N2 - The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. © 2009 American Chemical Society.

AB - The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. © 2009 American Chemical Society.

UR - https://www.mendeley.com/catalogue/079f87bf-af44-3f57-8db0-9f73aaf45011/

U2 - 10.1021/la902659w

DO - 10.1021/la902659w

M3 - Article

SN - 0743-7463

VL - 26

SP - 1904

EP - 1909

JO - Langmuir

JF - Langmuir

IS - 3

ER -

Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents

Abstrakti

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