Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

Päivi Mäki-Arvela; Jyri-Pekka Mikkola; Pasi Virtanen; Hannu Karhu; Tapio Salmi; Dmitry Yu. Murzin

doi:10.1016/S0167-2991(06)80894-3

Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

Päivi Mäki-Arvela^*, Jyri-Pekka Mikkola, Pasi Virtanen, Hannu Karhu, Tapio Salmi, Dmitry Yu. Murzin

^*Tämän työn vastaava kirjoittaja

Teknillisen kemian ja reaktiotekniikan laboratorio

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussa › Luku › Tieteellinen › vertaisarvioitu

9 Sitaatiot (Scopus)

Abstrakti

The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy⁺BF^- ₄Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to Pd^IV, whereas after three-phase citral hydrogenation it was close to Pd^II. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

Alkuperäiskieli	Englanti
Otsikko	Scientific Bases for the Preparation of Heterogeneous Catalysts
Toimittajat	E. M. Gaigneaux, M. Devillers, D. E. De Vos, S. Hermans, P. A. Jacobs, J. A. Martens, P. Ruiz
Kustantaja	Elsevier
Sivut	87-94
Sivumäärä	8
ISBN (painettu)	044452827X, 978-0-444-52827-8
DOI - pysyväislinkit	https://doi.org/10.1016/S0167-2991(06)80894-3
Tila	Julkaistu - 2006
OKM-julkaisutyyppi	A3 Kirjan osa tai toinen tutkimuskirja

Julkaisusarja

Nimi	Studies in Surface Science and Catalysis
Vuosikerta	162
ISSN (painettu)	0167-2991

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10.1016/S0167-2991(06)80894-3Lisenssi: Publisher rights policy

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Mäki-Arvela, P., Mikkola, J.-P., Virtanen, P., Karhu, H., Salmi, T., & Murzin, D. Y. (2006). Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. teoksessa E. M. Gaigneaux, M. Devillers, D. E. De Vos, S. Hermans, P. A. Jacobs, J. A. Martens, & P. Ruiz (Toimittajat), Scientific Bases for the Preparation of Heterogeneous Catalysts (Sivut 87-94). (Studies in Surface Science and Catalysis; Vuosikerta 162). Elsevier. https://doi.org/10.1016/S0167-2991(06)80894-3

Mäki-Arvela, Päivi ; Mikkola, Jyri-Pekka ; Virtanen, Pasi et al. / Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. Scientific Bases for the Preparation of Heterogeneous Catalysts. Toimittaja / E. M. Gaigneaux ; M. Devillers ; D. E. De Vos ; S. Hermans ; P. A. Jacobs ; J. A. Martens ; P. Ruiz. Elsevier, 2006. Sivut 87-94 (Studies in Surface Science and Catalysis).

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title = "Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral",

abstract = "The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.",

author = "P{\"a}ivi M{\"a}ki-Arvela and Jyri-Pekka Mikkola and Pasi Virtanen and Hannu Karhu and Tapio Salmi and Murzin, {Dmitry Yu.}",

year = "2006",

doi = "10.1016/S0167-2991(06)80894-3",

language = "English",

isbn = "044452827X",

series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier",

pages = "87--94",

editor = "Gaigneaux, {E. M.} and M. Devillers and {De Vos}, {D. E.} and S. Hermans and Jacobs, {P. A.} and Martens, {J. A.} and P. Ruiz",

booktitle = "Scientific Bases for the Preparation of Heterogeneous Catalysts",

address = "Netherlands",

}

Mäki-Arvela, P , Mikkola, J-P , Virtanen, P, Karhu, H, Salmi, T & Murzin, DY 2006, Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. julkaisussa EM Gaigneaux, M Devillers, DE De Vos, S Hermans, PA Jacobs, JA Martens & P Ruiz (toim), Scientific Bases for the Preparation of Heterogeneous Catalysts. Studies in Surface Science and Catalysis, Vuosikerta 162, Elsevier, Sivut 87-94. https://doi.org/10.1016/S0167-2991(06)80894-3

Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. / Mäki-Arvela, Päivi ; Mikkola, Jyri-Pekka ; Virtanen, Pasi et al.
Scientific Bases for the Preparation of Heterogeneous Catalysts. toim. / E. M. Gaigneaux; M. Devillers; D. E. De Vos; S. Hermans; P. A. Jacobs; J. A. Martens; P. Ruiz. Elsevier, 2006. s. 87-94 (Studies in Surface Science and Catalysis; Vuosikerta 162).

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussa › Luku › Tieteellinen › vertaisarvioitu

TY - CHAP

T1 - Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

AU - Mäki-Arvela, Päivi

AU - Mikkola, Jyri-Pekka

AU - Virtanen, Pasi

AU - Karhu, Hannu

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu.

PY - 2006

Y1 - 2006

N2 - The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

AB - The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

UR - http://www.scopus.com/inward/record.url?scp=35048886172&partnerID=8YFLogxK

U2 - 10.1016/S0167-2991(06)80894-3

DO - 10.1016/S0167-2991(06)80894-3

M3 - Chapter

AN - SCOPUS:35048886172

SN - 044452827X

SN - 978-0-444-52827-8

T3 - Studies in Surface Science and Catalysis

SP - 87

EP - 94

BT - Scientific Bases for the Preparation of Heterogeneous Catalysts

A2 - Gaigneaux, E. M.

A2 - Devillers, M.

A2 - De Vos, D. E.

A2 - Hermans, S.

A2 - Jacobs, P. A.

A2 - Martens, J. A.

A2 - Ruiz, P.

PB - Elsevier

ER -

Mäki-Arvela P , Mikkola JP , Virtanen P, Karhu H, Salmi T , Murzin DY. Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. julkaisussa Gaigneaux EM, Devillers M, De Vos DE, Hermans S, Jacobs PA, Martens JA, Ruiz P, toimittajat, Scientific Bases for the Preparation of Heterogeneous Catalysts. Elsevier. 2006. s. 87-94. (Studies in Surface Science and Catalysis). doi: 10.1016/S0167-2991(06)80894-3

Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

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