Structure sensitivity in heterogeneous catalysis with noncompetitive adsorption of reactants: Selective oxidation of lignan hydroxymatairesinol to oxomatairesinol over gold catalysts

Olga Simakova, Elena Murzina, Dmitry Murzin

    Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

    7 Sitaatiot (Scopus)

    Abstrakti

    Structure sensitivity in heterogeneous catalytic oxidative dehydrogenation of lignan hydroxymatairesinol (HMR) extracted from Norway spruce knots was investigated over a series of alumina-supported gold catalysts. A mathematical model was developed based on the concept of noncompetitive adsorption of reactants. The model, being consistent with kinetic regularities, such as reaction orders in reactants, explains well the dependence of catalytic activity on the gold cluster size.
    AlkuperäiskieliEi tiedossa
    Sivut770–774
    JulkaisuComptes Rendus Chimie
    Vuosikerta17
    Numero7-8
    DOI - pysyväislinkit
    TilaJulkaistu - 2014
    OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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