Structure effect of modified biochar in Ru/C catalysts for sugar mixture hydrogenation

J. L. Santos; L. M. Sanz-Moral; A. Aho; S. Ivanova; D. Yu Murzin; M. A. Centeno

doi:10.1016/j.biombioe.2022.106504

Structure effect of modified biochar in Ru/C catalysts for sugar mixture hydrogenation

J. L. Santos^*
, L. M. Sanz-Moral
, A. Aho
, S. Ivanova
, D. Yu Murzin
, M. A. Centeno

^*Tämän työn vastaava kirjoittaja

Teknillisen kemian ja reaktiotekniikan laboratorio

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

8 Sitaatiot (Scopus)

Abstrakti

This study deals with the production and activation of biochars and their use as supports for a series of ruthenium catalysts for hydrogenation of L-arabinose/D-galactose sugar mixture. The synthesized biochars differ in physicochemical properties and surface chemistry influencing ruthenium metal uptake and dispersion and as a consequence its catalytic behaviour. Selectivity exceeding 95% was observed for both hexitols. The catalytic performance of the prepared Ru supported catalysts is also compared to the already known Ru/activated carbon commercial catalyst.

Alkuperäiskieli	Englanti
Artikkeli	106504
Sivumäärä	9
Julkaisu	Biomass and Bioenergy
Vuosikerta	163
DOI - pysyväislinkit	https://doi.org/10.1016/j.biombioe.2022.106504
Tila	Julkaistu - elok. 2022
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Rahoitus

Five ruthenium catalysts (2 wt % nominal loading) were prepared using the set of carbonaceous supports by wetness impregnation of an acetone solution of ruthenium (III) nitrosyl nitrate (Johnson Matthey; purity = 14.34%). In a typical preparation, dried biochar was deposited in a mortar and appropriate volume of 1·10−3 M metal precursor were mixed dropwise. Afterward, biochar was dried at 100 °C overnight and activated at 300 °C during 2 h under reductant atmosphere (1:1vol. N2/H2, 100 mL/min). The generated catalysts were labelled as Ru/Ccel, Ru/Ccel ZnCl2, Ru/Cvin, Ru/Cvin ZnCl2 and Ru/Cdarco. A commercial catalyst containing 4.6 wt% ruthenium on activated carbon (Ru/Ccomm, Degussa) was also included in the series.Financial support for this work was obtained from Spanish Ministerio de Ciencia e Innovación (MICCIN) (Grant PID2020-113809RB-C32) and Junta de Andalucía via Consejería de Transformación Económica, Industria, Conocimiento y Universidades and its PAIDI 2020 program (Grant: P18-RT-3405) all co-financed by FEDER funds from the European Union. Financial support for this work was obtained from Spanish Ministerio de Ciencia e Innovación (MICCIN) (Grant PID2020-113809RB-C32 ) and Junta de Andalucía via Consejería de Transformación Económica, Industria , Conocimiento y Universidades and its PAIDI 2020 program (Grant: P18-RT-3405 ) all co-financed by FEDER funds from the European Union .

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10.1016/j.biombioe.2022.106504

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@article{ded1ef346d4d418ebee81c55da16a96d,

title = "Structure effect of modified biochar in Ru/C catalysts for sugar mixture hydrogenation",

abstract = "This study deals with the production and activation of biochars and their use as supports for a series of ruthenium catalysts for hydrogenation of L-arabinose/D-galactose sugar mixture. The synthesized biochars differ in physicochemical properties and surface chemistry influencing ruthenium metal uptake and dispersion and as a consequence its catalytic behaviour. Selectivity exceeding 95\% was observed for both hexitols. The catalytic performance of the prepared Ru supported catalysts is also compared to the already known Ru/activated carbon commercial catalyst.",

keywords = "Arabinose, Biomass valorization, Carbon supports, Galactose, Ruthenium catalysts",

author = "Santos, \{J. L.\} and Sanz-Moral, \{L. M.\} and A. Aho and S. Ivanova and Murzin, \{D. Yu\} and Centeno, \{M. A.\}",

note = "Funding Information: Five ruthenium catalysts (2 wt \% nominal loading) were prepared using the set of carbonaceous supports by wetness impregnation of an acetone solution of ruthenium (III) nitrosyl nitrate (Johnson Matthey; purity = 14.34\%). In a typical preparation, dried biochar was deposited in a mortar and appropriate volume of 1·10−3 M metal precursor were mixed dropwise. Afterward, biochar was dried at 100 °C overnight and activated at 300 °C during 2 h under reductant atmosphere (1:1vol. N2/H2, 100 mL/min). The generated catalysts were labelled as Ru/Ccel, Ru/Ccel ZnCl2, Ru/Cvin, Ru/Cvin ZnCl2 and Ru/Cdarco. A commercial catalyst containing 4.6 wt\% ruthenium on activated carbon (Ru/Ccomm, Degussa) was also included in the series.Financial support for this work was obtained from Spanish Ministerio de Ciencia e Innovaci{\'o}n (MICCIN) (Grant PID2020-113809RB-C32) and Junta de Andaluc{\'i}a via Consejer{\'i}a de Transformaci{\'o}n Econ{\'o}mica, Industria, Conocimiento y Universidades and its PAIDI 2020 program (Grant: P18-RT-3405) all co-financed by FEDER funds from the European Union. Funding Information: Financial support for this work was obtained from Spanish Ministerio de Ciencia e Innovaci{\'o}n (MICCIN) (Grant PID2020-113809RB-C32 ) and Junta de Andaluc{\'i}a via Consejer{\'i}a de Transformaci{\'o}n Econ{\'o}mica, Industria , Conocimiento y Universidades and its PAIDI 2020 program (Grant: P18-RT-3405 ) all co-financed by FEDER funds from the European Union . Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",

year = "2022",

month = aug,

doi = "10.1016/j.biombioe.2022.106504",

language = "English",

volume = "163",

journal = "Biomass and Bioenergy",

issn = "0961-9534",

publisher = "Elsevier",

}

TY - JOUR

T1 - Structure effect of modified biochar in Ru/C catalysts for sugar mixture hydrogenation

AU - Santos, J. L.

AU - Sanz-Moral, L. M.

AU - Aho, A.

AU - Ivanova, S.

AU - Murzin, D. Yu

AU - Centeno, M. A.

N1 - Funding Information: Five ruthenium catalysts (2 wt % nominal loading) were prepared using the set of carbonaceous supports by wetness impregnation of an acetone solution of ruthenium (III) nitrosyl nitrate (Johnson Matthey; purity = 14.34%). In a typical preparation, dried biochar was deposited in a mortar and appropriate volume of 1·10−3 M metal precursor were mixed dropwise. Afterward, biochar was dried at 100 °C overnight and activated at 300 °C during 2 h under reductant atmosphere (1:1vol. N2/H2, 100 mL/min). The generated catalysts were labelled as Ru/Ccel, Ru/Ccel ZnCl2, Ru/Cvin, Ru/Cvin ZnCl2 and Ru/Cdarco. A commercial catalyst containing 4.6 wt% ruthenium on activated carbon (Ru/Ccomm, Degussa) was also included in the series.Financial support for this work was obtained from Spanish Ministerio de Ciencia e Innovación (MICCIN) (Grant PID2020-113809RB-C32) and Junta de Andalucía via Consejería de Transformación Económica, Industria, Conocimiento y Universidades and its PAIDI 2020 program (Grant: P18-RT-3405) all co-financed by FEDER funds from the European Union. Funding Information: Financial support for this work was obtained from Spanish Ministerio de Ciencia e Innovación (MICCIN) (Grant PID2020-113809RB-C32 ) and Junta de Andalucía via Consejería de Transformación Económica, Industria , Conocimiento y Universidades and its PAIDI 2020 program (Grant: P18-RT-3405 ) all co-financed by FEDER funds from the European Union . Publisher Copyright: © 2022 Elsevier Ltd

PY - 2022/8

Y1 - 2022/8

N2 - This study deals with the production and activation of biochars and their use as supports for a series of ruthenium catalysts for hydrogenation of L-arabinose/D-galactose sugar mixture. The synthesized biochars differ in physicochemical properties and surface chemistry influencing ruthenium metal uptake and dispersion and as a consequence its catalytic behaviour. Selectivity exceeding 95% was observed for both hexitols. The catalytic performance of the prepared Ru supported catalysts is also compared to the already known Ru/activated carbon commercial catalyst.

AB - This study deals with the production and activation of biochars and their use as supports for a series of ruthenium catalysts for hydrogenation of L-arabinose/D-galactose sugar mixture. The synthesized biochars differ in physicochemical properties and surface chemistry influencing ruthenium metal uptake and dispersion and as a consequence its catalytic behaviour. Selectivity exceeding 95% was observed for both hexitols. The catalytic performance of the prepared Ru supported catalysts is also compared to the already known Ru/activated carbon commercial catalyst.

KW - Arabinose

KW - Biomass valorization

KW - Carbon supports

KW - Galactose

KW - Ruthenium catalysts

UR - https://www.scopus.com/pages/publications/85132320685

U2 - 10.1016/j.biombioe.2022.106504

DO - 10.1016/j.biombioe.2022.106504

M3 - Article

AN - SCOPUS:85132320685

SN - 0961-9534

VL - 163

JO - Biomass and Bioenergy

JF - Biomass and Bioenergy

M1 - 106504

ER -

Structure effect of modified biochar in Ru/C catalysts for sugar mixture hydrogenation

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