Solvent effects in catalysis: implementation for modelling of kinetics

Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

16 Sitaatiot (Scopus)

Abstrakti

A mathematical framework is developed for analysis of solvent dependent reaction rates in the case of complex catalytic reactions by incorporating solvent permittivity into the rate expressions. The theoretical approach was used to treat several generic reaction mechanisms and address also selectivity in various catalytic reactions. Comparison with representative data for homogeneous, heterogeneous and enzymatic catalysis shows applicability of the developed equations for describing activity and selectivity to accurately account for experimental observations.
AlkuperäiskieliEi tiedossa
Sivut5700–5713
JulkaisuCatalysis Science and Technology
Vuosikerta6
Numero14
DOI - pysyväislinkit
TilaJulkaistu - 2016
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

Keywords

  • engineering education

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