Revealing the role of stabilizers in H2O2 for the peroxyformic acid synthesis and decomposition kinetics

Tommaso Cogliano; Vincenzo Russo; Rosa Turco; Elio Santacesaria; Martino Di Serio; Tapio Salmi; Riccardo Tesser

doi:10.1016/j.ces.2022.117488

Revealing the role of stabilizers in H₂O₂ for the peroxyformic acid synthesis and decomposition kinetics

Tommaso Cogliano
, Vincenzo Russo^*
, Rosa Turco
, Elio Santacesaria
, Martino Di Serio
, Tapio Salmi
, Riccardo Tesser

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

9 Sitaatiot (Scopus)

Abstrakti

The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.

Alkuperäiskieli	Englanti
Artikkeli	117488
Julkaisu	Chemical Engineering Science
Vuosikerta	251
Varhainen verkossa julkaisun päivämäärä	2 helmik. 2022
DOI - pysyväislinkit	https://doi.org/10.1016/j.ces.2022.117488
Tila	Julkaistu - 6 huhtik. 2022
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Rahoitus

The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale – Bando 2017 – prot. number: 2017KBTK93 “CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)” of Italian Ministero dell'Istruzione dell'Università e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale ? Bando 2017 ? prot. number: 2017KBTK93 ?CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)? of Italian Ministero dell'Istruzione dell'Universit? e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions.

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@article{d72990f6df9a44db8b939f996b221ac7,

title = "Revealing the role of stabilizers in H2O2 for the peroxyformic acid synthesis and decomposition kinetics",

abstract = "The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.",

keywords = "Catalyzed reaction, Hydrogen peroxide, Kinetic modeling, Kinetics, Performic acid synthesis and decomposition, Stabilizers in HO",

author = "Tommaso Cogliano and Vincenzo Russo and Rosa Turco and Elio Santacesaria and \{Di Serio\}, Martino and Tapio Salmi and Riccardo Tesser",

note = "Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale – Bando 2017 – prot. number: 2017KBTK93 “CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)” of Italian Ministero dell'Istruzione dell'Universit{\`a} e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale ? Bando 2017 ? prot. number: 2017KBTK93 ?CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)? of Italian Ministero dell'Istruzione dell'Universit? e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",

year = "2022",

month = apr,

day = "6",

doi = "10.1016/j.ces.2022.117488",

language = "English",

volume = "251",

journal = "Chemical Engineering Science",

issn = "0009-2509",

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TY - JOUR

T1 - Revealing the role of stabilizers in H2O2 for the peroxyformic acid synthesis and decomposition kinetics

AU - Cogliano, Tommaso

AU - Russo, Vincenzo

AU - Turco, Rosa

AU - Santacesaria, Elio

AU - Di Serio, Martino

AU - Salmi, Tapio

AU - Tesser, Riccardo

N1 - Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale – Bando 2017 – prot. number: 2017KBTK93 “CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)” of Italian Ministero dell'Istruzione dell'Università e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale ? Bando 2017 ? prot. number: 2017KBTK93 ?CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)? of Italian Ministero dell'Istruzione dell'Universit? e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Publisher Copyright: © 2022 Elsevier Ltd

PY - 2022/4/6

Y1 - 2022/4/6

N2 - The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.

AB - The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.

KW - Catalyzed reaction

KW - Hydrogen peroxide

KW - Kinetic modeling

KW - Kinetics

KW - Performic acid synthesis and decomposition

KW - Stabilizers in HO

UR - https://www.scopus.com/pages/publications/85124035567

U2 - 10.1016/j.ces.2022.117488

DO - 10.1016/j.ces.2022.117488

M3 - Article

AN - SCOPUS:85124035567

SN - 0009-2509

VL - 251

JO - Chemical Engineering Science

JF - Chemical Engineering Science

M1 - 117488

ER -