Regioselective hydrogenation of 1,2-indanedione over heterogeneous Pd and Pt catalysts

Otto Långvik; Päivi Mäki-Arvela; Atte Aho; Tiina Saloranta; Dmitry Murzin; Reko Leino

doi:10.1007/s10562-012-0951-9

Regioselective hydrogenation of 1,2-indanedione over heterogeneous Pd and Pt catalysts

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

5 Sitaatiot (Scopus)

Abstrakti

Regioselective hydrogenation of 1,2-indanedione yielding rac-2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al2O3. Practical operation under atmospheric pressure of hydrogen at low temperature (40 A degrees C) for 120 min gave the desired product in > 99 % regioselectivity, 84 % conversion and 77 % yield, according to GC, using 2 mol% Pd/Al2O3 as the catalyst.

Alkuperäiskieli	Ei tiedossa
Sivut	142–149
Sivumäärä	8
Julkaisu	Catalysis Letters
Vuosikerta	143
Numero	2
DOI - pysyväislinkit	https://doi.org/10.1007/s10562-012-0951-9
Tila	Julkaistu - 2013
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Keywords

1,2-Indanedione
2-Hydroxy-1-indanone
Heterogeneous catalysis
Hydrogenation
Regioselectivity

Pääsy asiakirjaan

10.1007/s10562-012-0951-9

Viittausmuodot

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abstract = "Regioselective hydrogenation of 1,2-indanedione yielding rac-2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al2O3. Practical operation under atmospheric pressure of hydrogen at low temperature (40 A degrees C) for 120 min gave the desired product in > 99 \% regioselectivity, 84 \% conversion and 77 \% yield, according to GC, using 2 mol\% Pd/Al2O3 as the catalyst.",

keywords = "1,2-Indanedione, 2-Hydroxy-1-indanone, Heterogeneous catalysis, Hydrogenation, Regioselectivity, 1,2-Indanedione, 2-Hydroxy-1-indanone, Heterogeneous catalysis, Hydrogenation, Regioselectivity, 1,2-Indanedione, 2-Hydroxy-1-indanone, Heterogeneous catalysis, Hydrogenation, Regioselectivity",

author = "Otto L{\aa}ngvik and P{\"a}ivi M{\"a}ki-Arvela and Atte Aho and Tiina Saloranta and Dmitry Murzin and Reko Leino",

year = "2013",

doi = "10.1007/s10562-012-0951-9",

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TY - JOUR

T1 - Regioselective hydrogenation of 1,2-indanedione over heterogeneous Pd and Pt catalysts

AU - Långvik, Otto

AU - Mäki-Arvela, Päivi

AU - Aho, Atte

AU - Saloranta, Tiina

AU - Murzin, Dmitry

AU - Leino, Reko

PY - 2013

Y1 - 2013

N2 - Regioselective hydrogenation of 1,2-indanedione yielding rac-2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al2O3. Practical operation under atmospheric pressure of hydrogen at low temperature (40 A degrees C) for 120 min gave the desired product in > 99 % regioselectivity, 84 % conversion and 77 % yield, according to GC, using 2 mol% Pd/Al2O3 as the catalyst.

AB - Regioselective hydrogenation of 1,2-indanedione yielding rac-2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al2O3. Practical operation under atmospheric pressure of hydrogen at low temperature (40 A degrees C) for 120 min gave the desired product in > 99 % regioselectivity, 84 % conversion and 77 % yield, according to GC, using 2 mol% Pd/Al2O3 as the catalyst.

KW - 1,2-Indanedione

KW - 2-Hydroxy-1-indanone

KW - Heterogeneous catalysis

KW - Hydrogenation

KW - Regioselectivity

KW - 1,2-Indanedione

KW - 2-Hydroxy-1-indanone

KW - Heterogeneous catalysis

KW - Hydrogenation

KW - Regioselectivity

KW - 1,2-Indanedione

KW - 2-Hydroxy-1-indanone

KW - Heterogeneous catalysis

KW - Hydrogenation

KW - Regioselectivity

U2 - 10.1007/s10562-012-0951-9

DO - 10.1007/s10562-012-0951-9

M3 - Artikel

SN - 1011-372X

VL - 143

SP - 142

EP - 149

JO - Catalysis Letters

JF - Catalysis Letters

IS - 2

ER -