Abstrakti
Regioselective hydrogenation of 1,2-indanedione yielding rac-2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al2O3. Practical operation under atmospheric pressure of hydrogen at low temperature (40 A degrees C) for 120 min gave the desired product in > 99 % regioselectivity, 84 % conversion and 77 % yield, according to GC, using 2 mol% Pd/Al2O3 as the catalyst.
Alkuperäiskieli | Ei tiedossa |
---|---|
Sivut | 142–149 |
Sivumäärä | 8 |
Julkaisu | Catalysis Letters |
Vuosikerta | 143 |
Numero | 2 |
DOI - pysyväislinkit | |
Tila | Julkaistu - 2013 |
OKM-julkaisutyyppi | A1 Julkaistu artikkeli, soviteltu |
Keywords
- 1,2-Indanedione
- 2-Hydroxy-1-indanone
- Heterogeneous catalysis
- Hydrogenation
- Regioselectivity