Rate Equations of Structure-Sensitive Catalytic Reactions with Arbitrary Kinetics

Dmitry Yu Murzin

doi:10.3390/chemengineering7010012

Rate Equations of Structure-Sensitive Catalytic Reactions with Arbitrary Kinetics

Dmitry Yu Murzin^*

^*Tämän työn vastaava kirjoittaja

Teknillisen kemian ja reaktiotekniikan laboratorio

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

27 Lataukset (Pure)

Abstrakti

A general mathematical framework for the quantitative description of the cluster size dependence in heterogeneous catalytic reactions has been developed based on an analysis of the Gibbs energy of elementary reactions. The methodology was illustrated for a generic linear sequence of elementary reactions with three steps, a multi-step mechanism of ethanol oxidation comprising linear, nonlinear and quasi-equilibria steps and a network of parallel reactions in transformations of furfural.

Alkuperäiskieli	Englanti
Artikkeli	12
Sivumäärä	10
Julkaisu	ChemEngineering
Vuosikerta	7
Numero	1
DOI - pysyväislinkit	https://doi.org/10.3390/chemengineering7010012
Tila	Julkaistu - helmik. 2023
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.3390/chemengineering7010012

ChemEngineering-07-00012Lopullinen julkaistu versio, 465 KBLisenssi: CC BY

https://urn.fi/URN:NBN:fi-fe202401304790

Muut tiedostot ja linkit

Linkki julkaisuun Scopuksessa

Viittausmuodot

@article{dc865864971b4e04adeef018015804c7,

title = "Rate Equations of Structure-Sensitive Catalytic Reactions with Arbitrary Kinetics",

abstract = "A general mathematical framework for the quantitative description of the cluster size dependence in heterogeneous catalytic reactions has been developed based on an analysis of the Gibbs energy of elementary reactions. The methodology was illustrated for a generic linear sequence of elementary reactions with three steps, a multi-step mechanism of ethanol oxidation comprising linear, nonlinear and quasi-equilibria steps and a network of parallel reactions in transformations of furfural.",

keywords = "arbitrary kinetics, parallel reactions, rate equations, structure sensitivity, structure sensitivity, arbitrary kinetics, parallel reactions, rate equations",

author = "Murzin, {Dmitry Yu}",

note = "Publisher Copyright: {\textcopyright} 2023 by the author.",

year = "2023",

month = feb,

doi = "10.3390/chemengineering7010012",

language = "English",

volume = "7",

journal = "ChemEngineering",

issn = "2305-7084",

publisher = "MDPI",

number = "1",

}

TY - JOUR

T1 - Rate Equations of Structure-Sensitive Catalytic Reactions with Arbitrary Kinetics

AU - Murzin, Dmitry Yu

PY - 2023/2

Y1 - 2023/2

N2 - A general mathematical framework for the quantitative description of the cluster size dependence in heterogeneous catalytic reactions has been developed based on an analysis of the Gibbs energy of elementary reactions. The methodology was illustrated for a generic linear sequence of elementary reactions with three steps, a multi-step mechanism of ethanol oxidation comprising linear, nonlinear and quasi-equilibria steps and a network of parallel reactions in transformations of furfural.

AB - A general mathematical framework for the quantitative description of the cluster size dependence in heterogeneous catalytic reactions has been developed based on an analysis of the Gibbs energy of elementary reactions. The methodology was illustrated for a generic linear sequence of elementary reactions with three steps, a multi-step mechanism of ethanol oxidation comprising linear, nonlinear and quasi-equilibria steps and a network of parallel reactions in transformations of furfural.

KW - arbitrary kinetics

KW - parallel reactions

KW - rate equations

KW - structure sensitivity

KW - arbitrary kinetics

KW - parallel reactions

KW - rate equations

UR - http://www.scopus.com/inward/record.url?scp=85148939758&partnerID=8YFLogxK

U2 - 10.3390/chemengineering7010012

DO - 10.3390/chemengineering7010012

M3 - Article

AN - SCOPUS:85148939758

SN - 2305-7084

VL - 7

JO - ChemEngineering

JF - ChemEngineering

IS - 1

M1 - 12

ER -

Rate Equations of Structure-Sensitive Catalytic Reactions with Arbitrary Kinetics

Abstrakti

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Viittausmuodot