Production of diesel fuel from renewable feeds: Kinetics of ethyl stearate decarboxylation

M. Snåre; I. Kubičková; P. Mäki-Arvela; K. Eränen; J. Wärnå; D. Yu. Murzin

doi:10.1016/j.cej.2007.03.064

Production of diesel fuel from renewable feeds: Kinetics of ethyl stearate decarboxylation

M. Snåre, I. Kubičková, P. Mäki-Arvela, K. Eränen, J. Wärnå, D. Yu. Murzin^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

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The kinetics of liquid phase ethyl stearate decarboxylation for production of diesel fuel hydrocarbons was studied over a Pd/C catalyst in a semi-batch reactor. The kinetic behavior was tested in a wide range of temperature. Furthermore a supplementary investigation of the reaction intermediate, stearic acid, was performed. The main kinetic regularities were established in both cases. Finally successful kinetic modeling and parameter estimation was performed based on the proposed reaction route. The predicted results explained the experimental results well.

Alkuperäiskieli	Englanti
Sivut	29-34
Sivumäärä	6
Julkaisu	Chemical Engineering Journal
Vuosikerta	134
Numero	1-3
DOI - pysyväislinkit	https://doi.org/10.1016/j.cej.2007.03.064
Tila	Julkaistu - 1 marrask. 2007
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

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title = "Production of diesel fuel from renewable feeds: Kinetics of ethyl stearate decarboxylation",

abstract = "The kinetics of liquid phase ethyl stearate decarboxylation for production of diesel fuel hydrocarbons was studied over a Pd/C catalyst in a semi-batch reactor. The kinetic behavior was tested in a wide range of temperature. Furthermore a supplementary investigation of the reaction intermediate, stearic acid, was performed. The main kinetic regularities were established in both cases. Finally successful kinetic modeling and parameter estimation was performed based on the proposed reaction route. The predicted results explained the experimental results well.",

keywords = "Biodiesel, Decarboxylation, Stearic acid",

author = "M. Sn{\aa}re and I. Kubi{\v c}kov{\'a} and P. M{\"a}ki-Arvela and K. Er{\"a}nen and J. W{\"a}rn{\aa} and Murzin, {D. Yu.}",

year = "2007",

month = nov,

day = "1",

doi = "10.1016/j.cej.2007.03.064",

language = "English",

volume = "134",

pages = "29--34",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

publisher = "Elsevier",

number = "1-3",

}

TY - JOUR

T1 - Production of diesel fuel from renewable feeds

T2 - Kinetics of ethyl stearate decarboxylation

AU - Snåre, M.

AU - Kubičková, I.

AU - Mäki-Arvela, P.

AU - Eränen, K.

AU - Wärnå, J.

AU - Murzin, D. Yu.

PY - 2007/11/1

Y1 - 2007/11/1

N2 - The kinetics of liquid phase ethyl stearate decarboxylation for production of diesel fuel hydrocarbons was studied over a Pd/C catalyst in a semi-batch reactor. The kinetic behavior was tested in a wide range of temperature. Furthermore a supplementary investigation of the reaction intermediate, stearic acid, was performed. The main kinetic regularities were established in both cases. Finally successful kinetic modeling and parameter estimation was performed based on the proposed reaction route. The predicted results explained the experimental results well.

AB - The kinetics of liquid phase ethyl stearate decarboxylation for production of diesel fuel hydrocarbons was studied over a Pd/C catalyst in a semi-batch reactor. The kinetic behavior was tested in a wide range of temperature. Furthermore a supplementary investigation of the reaction intermediate, stearic acid, was performed. The main kinetic regularities were established in both cases. Finally successful kinetic modeling and parameter estimation was performed based on the proposed reaction route. The predicted results explained the experimental results well.

KW - Biodiesel

KW - Decarboxylation

KW - Stearic acid

UR - http://www.scopus.com/inward/record.url?scp=34548275501&partnerID=8YFLogxK

U2 - 10.1016/j.cej.2007.03.064

DO - 10.1016/j.cej.2007.03.064

M3 - Article

AN - SCOPUS:34548275501

SN - 1385-8947

VL - 134

SP - 29

EP - 34

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

IS - 1-3

ER -

Production of diesel fuel from renewable feeds: Kinetics of ethyl stearate decarboxylation

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