Photothermally Responsive Inks for Inkjet-Printing Secure Information

Giuseppe Chirico, Giacomo Dacarro, Colm O’Regan, Jouko Peltonen, Jawad Sarfraz, Angelo Taglietti, Mykola Borzenkov, Piersandro Pallavicini

Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

6 Sitaatiot (Scopus)

Abstrakti

2D patterns of photothermally responsive near-infrared (NIR) absorbing gold nanostars (GNS), coated with multiple charged polymer layers, are inkjetprinted on a glass surface. The shape of the localized surface plasmon resonance (LSPR) NIR absorption bands in the printed patterns loses its peakedform due to plasmon coupling, unless GNS are enveloped in multiple coating layers, keeping the inter-GNS distance sufficiently large. In the latter case, the photothermal temperature increase (ΔT) induced by the NIR laser irradiation follows a ΔT versus irradiation wavelength (λirr) profile with the same sharply peaked shape of the LSPR bands of the liquid ink. With this result, a new paradigm for inkjet-writing secure information is introduced, as an alternative to the current methods based on direct visual inspection of printed patterns.While the printed ink patterns of GNS with different coatings are visually indistinguishable despite their different NIR absorption spectrum, their photothermal response changes dramatically with λirr. This allows either to write and read simple information using a single λirr (YES answer for ΔT > threshold) or to use multiple λirr to write and read complex information like thermal bar codes and anti-counterfeit signatures.

AlkuperäiskieliEi tiedossa
Sivut1800095-1–1800095-6
JulkaisuParticle and Particle Systems Characterization
Vuosikerta35
Numero9
DOI - pysyväislinkit
TilaJulkaistu - 2018
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

Keywords

  • Materials science
  • Nanostructured materials
  • Inkjet printing
  • Photothermal effect

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