Paving the path toward silicon as anode material for future solid-state batteries

Palanivel Molaiyan; Buket  Boz; Glaydson Simoes dos Reis; Rafaz  Sliz; Shuo Wang; Marco Borsari; Ulla Lassi; Andrea Paolella

doi:10.1016/j.etran.2024.100391

Paving the path toward silicon as anode material for future solid-state batteries

Palanivel Molaiyan
, Buket Boz
, Glaydson Simoes dos Reis
, Rafaz Sliz
, Shuo Wang
, Marco Borsari
, Ulla Lassi
, Andrea Paolella

Teknillisen kemian ja reaktiotekniikan laboratorio

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

23 Sitaatiot (Scopus)

139 Lataukset (Pure)

Abstrakti

Solid-state batteries (SSBs) have emerged as an important technology for powering future electric vehicles and other applications due to their potential for enhanced safety and higher energy density compared to lithium-ion batteries (LIBs). Among future energy storage systems, SSBs (either semi or full SSBs) are the most promising candidates in terms of safety, cost, performance, and compactness. There has been a great effort to utilize silicon (Si) anode in SSBs due to its high specific capacity (3590 mAh g ⁻¹), low cost, and earth abundance. SSBs with silicon anodes displayed attractive application prospects. The current research efforts showed that there is a great need to understand electrochemical performance, especially the interphase behavior, Si material design, and advanced tools for analytical characterization. In this review, we provide insights about the Si anode design, interface issues, SEI formation, failure mechanisms, and material modifications for the development of next-generation Si-based SSBs of use to bridge the gap between applied research and industrial scale applications.

Alkuperäiskieli	Englanti
Artikkeli	100391
Julkaisu	eTransportation
Vuosikerta	23
DOI - pysyväislinkit	https://doi.org/10.1016/j.etran.2024.100391
Tila	Julkaistu - 8 tammik. 2025
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Rahoitus

P.M. gratefully acknowledges financial support from the Research Council of Finland (Academy Research Fellows 2024, Project In2BaT, grant no. 362298). G.S., R.S., and U.L. gratefully acknowledge the financial support of the EU/Interreg Aurora (Project GreenBattery, grant no 20357574). Dr. Glaydson dos Simoes Reis gratefully acknowledges financial support from the Research Council of Finland (Academy Research Fellows 2024, Project: Bio-Adsorb&Energy, grant no. 361583). S.W. acknowledges the Natural Science Foundation of China (grant no. 52302305), Guangdong Basic and Applied Basic Research Foundation (Grant No. 2021A1515110312), Natural Science Foundation Exploration Program of Wuhan (Morning Light Plan) (grant no. 202401jc0089), and support from Tong Xiang Advanced New Materials Institute.

Pääsy asiakirjaan

10.1016/j.etran.2024.100391Lisenssi: CC BY

1-s2.0-S259011682400081X-mainLopullinen julkaistu versio, 10,2 MBLisenssi: CC BY

https://urn.fi/URN:NBN:fi-fe2025040122706

Viittausmuodot

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title = "Paving the path toward silicon as anode material for future solid-state batteries",

abstract = "Solid-state batteries (SSBs) have emerged as an important technology for powering future electric vehicles and other applications due to their potential for enhanced safety and higher energy density compared to lithium-ion batteries (LIBs). Among future energy storage systems, SSBs (either semi or full SSBs) are the most promising candidates in terms of safety, cost, performance, and compactness. There has been a great effort to utilize silicon (Si) anode in SSBs due to its high specific capacity (3590 mAh g −1), low cost, and earth abundance. SSBs with silicon anodes displayed attractive application prospects. The current research efforts showed that there is a great need to understand electrochemical performance, especially the interphase behavior, Si material design, and advanced tools for analytical characterization. In this review, we provide insights about the Si anode design, interface issues, SEI formation, failure mechanisms, and material modifications for the development of next-generation Si-based SSBs of use to bridge the gap between applied research and industrial scale applications.",

author = "Palanivel Molaiyan and Buket Boz and \{Simoes dos Reis\}, Glaydson and Rafaz Sliz and Shuo Wang and Marco Borsari and Ulla Lassi and Andrea Paolella",

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month = jan,

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doi = "10.1016/j.etran.2024.100391",

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T1 - Paving the path toward silicon as anode material for future solid-state batteries

AU - Molaiyan, Palanivel

AU - Boz, Buket

AU - Simoes dos Reis, Glaydson

AU - Sliz, Rafaz

AU - Wang, Shuo

AU - Borsari, Marco

AU - Lassi, Ulla

AU - Paolella, Andrea

PY - 2025/1/8

Y1 - 2025/1/8

N2 - Solid-state batteries (SSBs) have emerged as an important technology for powering future electric vehicles and other applications due to their potential for enhanced safety and higher energy density compared to lithium-ion batteries (LIBs). Among future energy storage systems, SSBs (either semi or full SSBs) are the most promising candidates in terms of safety, cost, performance, and compactness. There has been a great effort to utilize silicon (Si) anode in SSBs due to its high specific capacity (3590 mAh g −1), low cost, and earth abundance. SSBs with silicon anodes displayed attractive application prospects. The current research efforts showed that there is a great need to understand electrochemical performance, especially the interphase behavior, Si material design, and advanced tools for analytical characterization. In this review, we provide insights about the Si anode design, interface issues, SEI formation, failure mechanisms, and material modifications for the development of next-generation Si-based SSBs of use to bridge the gap between applied research and industrial scale applications.

AB - Solid-state batteries (SSBs) have emerged as an important technology for powering future electric vehicles and other applications due to their potential for enhanced safety and higher energy density compared to lithium-ion batteries (LIBs). Among future energy storage systems, SSBs (either semi or full SSBs) are the most promising candidates in terms of safety, cost, performance, and compactness. There has been a great effort to utilize silicon (Si) anode in SSBs due to its high specific capacity (3590 mAh g −1), low cost, and earth abundance. SSBs with silicon anodes displayed attractive application prospects. The current research efforts showed that there is a great need to understand electrochemical performance, especially the interphase behavior, Si material design, and advanced tools for analytical characterization. In this review, we provide insights about the Si anode design, interface issues, SEI formation, failure mechanisms, and material modifications for the development of next-generation Si-based SSBs of use to bridge the gap between applied research and industrial scale applications.

U2 - 10.1016/j.etran.2024.100391

DO - 10.1016/j.etran.2024.100391

M3 - Article

SN - 2590-1168

VL - 23

JO - eTransportation

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M1 - 100391

ER -

Paving the path toward silicon as anode material for future solid-state batteries

Abstrakti

Rahoitus

Pääsy asiakirjaan

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Viittausmuodot