Opening of monoterpene epoxide to a potent anti-Parkinson compound of para-menthane structure over heterogeneous catalysts

Martina Stekrova; Narendra Kumar; Päivi Mäki-Arvela; Atte Aho; Johan Linden; Konstantin P. Volcho; Nariman F. Salakhutdinov; Dmitry Yu Murzin

doi:10.1007/s11144-013-0615-9

Opening of monoterpene epoxide to a potent anti-Parkinson compound of para-menthane structure over heterogeneous catalysts

Martina Stekrova, Narendra Kumar, Päivi Mäki-Arvela, Atte Aho, Johan Linden, Konstantin P. Volcho, Nariman F. Salakhutdinov, Dmitry Yu Murzin^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

16 Sitaatiot (Scopus)

Abstrakti

High selectivity (82 %) to 3-methyl-6-(prop-1-en-2-yl)cyclohex-3-ene- 1,2-diol, a potent anti-Parkinson drug, was achieved in the isomerization of verbenol oxide at the conversion level of 96 % in N,N-dimethylacetamide at 140 °C over a metal modified zeolite, Fe-Beta-300 with SiO₂ to Al2O₃ ratio of 300. This catalyst exhibits both weak and medium strong Brønsted and Lewis acid sites.

Alkuperäiskieli	Englanti
Sivut	449-458
Sivumäärä	10
Julkaisu	Reaction Kinetics, Mechanisms and Catalysis
Vuosikerta	110
Numero	2
DOI - pysyväislinkit	https://doi.org/10.1007/s11144-013-0615-9
Tila	Julkaistu - elok. 2013
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1007/s11144-013-0615-9

Muut tiedostot ja linkit

Link to publication in Scopus

Viittausmuodot

@article{18dd34a530c645979b25f44a98cce84d,

title = "Opening of monoterpene epoxide to a potent anti-Parkinson compound of para-menthane structure over heterogeneous catalysts",

abstract = "High selectivity (82 %) to 3-methyl-6-(prop-1-en-2-yl)cyclohex-3-ene- 1,2-diol, a potent anti-Parkinson drug, was achieved in the isomerization of verbenol oxide at the conversion level of 96 % in N,N-dimethylacetamide at 140 °C over a metal modified zeolite, Fe-Beta-300 with SiO2 to Al2O3 ratio of 300. This catalyst exhibits both weak and medium strong Br{\o}nsted and Lewis acid sites.",

keywords = "Isomerization, Mesoporous material, Verbenol oxide, Zeolite",

author = "Martina Stekrova and Narendra Kumar and P{\"a}ivi M{\"a}ki-Arvela and Atte Aho and Johan Linden and Volcho, {Konstantin P.} and Salakhutdinov, {Nariman F.} and Murzin, {Dmitry Yu}",

year = "2013",

month = aug,

doi = "10.1007/s11144-013-0615-9",

language = "English",

volume = "110",

pages = "449--458",

journal = "Reaction Kinetics, Mechanisms and Catalysis",

issn = "1878-5190",

publisher = "Akademiai Kiado",

number = "2",

}

Opening of monoterpene epoxide to a potent anti-Parkinson compound of para-menthane structure over heterogeneous catalysts. / Stekrova, Martina; Kumar, Narendra ; Mäki-Arvela, Päivi et al.
julkaisussa: Reaction Kinetics, Mechanisms and Catalysis, Vuosikerta 110, Nro 2, 08.2013, s. 449-458.

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

TY - JOUR

T1 - Opening of monoterpene epoxide to a potent anti-Parkinson compound of para-menthane structure over heterogeneous catalysts

AU - Stekrova, Martina

AU - Kumar, Narendra

AU - Mäki-Arvela, Päivi

AU - Aho, Atte

AU - Linden, Johan

AU - Volcho, Konstantin P.

AU - Salakhutdinov, Nariman F.

AU - Murzin, Dmitry Yu

PY - 2013/8

Y1 - 2013/8

N2 - High selectivity (82 %) to 3-methyl-6-(prop-1-en-2-yl)cyclohex-3-ene- 1,2-diol, a potent anti-Parkinson drug, was achieved in the isomerization of verbenol oxide at the conversion level of 96 % in N,N-dimethylacetamide at 140 °C over a metal modified zeolite, Fe-Beta-300 with SiO2 to Al2O3 ratio of 300. This catalyst exhibits both weak and medium strong Brønsted and Lewis acid sites.

AB - High selectivity (82 %) to 3-methyl-6-(prop-1-en-2-yl)cyclohex-3-ene- 1,2-diol, a potent anti-Parkinson drug, was achieved in the isomerization of verbenol oxide at the conversion level of 96 % in N,N-dimethylacetamide at 140 °C over a metal modified zeolite, Fe-Beta-300 with SiO2 to Al2O3 ratio of 300. This catalyst exhibits both weak and medium strong Brønsted and Lewis acid sites.

KW - Isomerization

KW - Mesoporous material

KW - Verbenol oxide

KW - Zeolite

UR - http://www.scopus.com/inward/record.url?scp=84893707379&partnerID=8YFLogxK

U2 - 10.1007/s11144-013-0615-9

DO - 10.1007/s11144-013-0615-9

M3 - Article

AN - SCOPUS:84893707379

SN - 1878-5190

VL - 110

SP - 449

EP - 458

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

IS - 2

ER -

Opening of monoterpene epoxide to a potent anti-Parkinson compound of para-menthane structure over heterogeneous catalysts

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