Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors

Mykola Moroz; Pavlo Demchenko; Myroslava Prokhorenko; Bohdan Rudyk; Oleksiy  Garashchenko; Serhiy Prokhorenko; Oleksandr  Lazarenko; Oleksandr Reshetnyak; Fiseha Tesfaye; Leena Hupa

doi:10.1007/978-3-031-80688-9_25

Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors

Mykola Moroz^*
, Pavlo Demchenko
, Myroslava Prokhorenko
, Bohdan Rudyk
, Oleksiy Garashchenko
, Serhiy Prokhorenko
, Oleksandr Lazarenko
, Oleksandr Reshetnyak
, Fiseha Tesfaye
, Leena Hupa

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussa › Konferenssiartikkeli › Tieteellinen › vertaisarvioitu

17 Lataukset (Pure)

Abstrakti

In this study, the low-temperature synthesis and thermodynamic propertiesThermodynamic properties of the AgGaGeS ₄ compound were analyzed in detail for potential applications in optoelectronicsOptoelectronic compounds and gas sensorsGas sensors. The existence of two four-phase regions Ge–GeS–Ga ₂S ₃–AgGaGeS ₄ and GeS–GeS ₂–Ga ₂S ₃–AgGaGeS ₄ in the Ge–GeS ₂–Ga ₂S ₃–AgGaS ₂ part of the Ag–Ga–Ge–S system, which are in equilibrium below (540 ± 5) K, has been confirmed through the modified electromotive force (EMF) method. The spatial position of the four-phase regions relative to the silver point was employed to ascertain the overall potential-forming reactions of the AgGaGeS ₄ synthesis from mixtures of silver, germanium, and compounds (Ga ₂S ₃, GeS, GeS ₂, AgGaS ₂) in the positive electrodes of electrochemical cells. Based on the results obtained, the temperature dependences of the EMF of electrochemical cells were used to determine the values of standard thermodynamic functions (Gibbs energyGibbs energy, enthalpy, and entropy) of the AgGaGeS ₄ compound.

Alkuperäiskieli	Englanti
Otsikko	Energy Technology 2025 - Carbon Dioxide Management and Other Technologies
Alaotsikko	Carbon Dioxide Management and Other Technologies
Toimittajat	Onuralp Yücel, Chukwunwike Iloeje, Shafiq Alam, Donna Post Guillen, Fiseha Tesfaye, Lei Zhang, Susanna A. C. Hockaday, Neale R. Neelameggham, Hong Peng, Nawshad Haque, Alafara Abdullahi Baba, Tuan A. H. Nguyen, Adam C. Powell, Duhan Zhang
Julkaisupaikka	Switzerland
Kustantaja	Springer, Cham
Sivut	267-277
Sivumäärä	11
Vuosikerta	1
Painos	1
ISBN (elektroninen)	978-3-031-80688-9
ISBN (painettu)	978-3-031-80688-9, 978-3-031-80687-2, 978-3-031-80690-2
DOI - pysyväislinkit	https://doi.org/10.1007/978-3-031-80688-9_25
Tila	Julkaistu - 2025
OKM-julkaisutyyppi	A4 Artikkeli konferenssijulkaisuussa

Julkaisusarja

Nimi	The Minerals, Metals & Materials Series
Kustantaja	Springer Cham
Numero	1
Vuosikerta	1
ISSN (painettu)	2367-1181
ISSN (elektroninen)	2367-1696

Rahoitus

The authors express their gratitude for the financial support provided by the grants of Ministry of Education and Science of Ukraine: No\u00A00124U001146 \u201CNew dual-purpose materials with effective electrical properties\u201D and No\u00A00123U101857 \u201CPhysico-chemistry of functional nanomaterials for electrochemical systems\u201D.

YK:n kestävän kehityksen tavoitteet

Tämä tuotos edistää seuraavia kestävän kehityksen tavoitteita:

SDG 11 – Kestävät kaupungit ja yhteisöt

Pääsy asiakirjaan

10.1007/978-3-031-80688-9_25

M196416 (1)Hyväksytty kirjoittajan käsikirjoitus, 889 KBLisenssi: All rights reserved

https://urn.fi/URN:NBN:fi-fe2026031319542

GLCE: A step forward on greener and low-carbon extraction and recovery of non-ferrous metals
Tesfaye, F. (Vastuullinen tutkija), Vainio, E. (Vastuullinen tutkija) & Hupa, L. (Vastuullinen tutkija)
01/01/24 → 31/03/26
Projekti: Foundation

Energy Technologies and CO2 Management
Yucel, O. (Järjestäjä), Chukwunwike O., I. (Järjestäjä), Alam, S. (Järjestäjä), Guillen, D. (Järjestäjä), Tesfaye, F. (Järjestäjä), Zhang, L. (Järjestäjä), Neelameggham, N. R. (Osallistuja) & Peng, H. (Järjestäjä)
23 maalisk. 2025 → 27 maalisk. 2025
Aktiviteetti: Tapahtumaan osallistuminen tai tapahtuman järjestäminen › Konferenssin, symposiumin tai työpajan järjestäminen

Tiedosto

Viittausmuodot

Moroz, M., Demchenko, P., Prokhorenko, M., Rudyk, B., Garashchenko, O., Prokhorenko, S., Lazarenko, O., Reshetnyak, O., Tesfaye, F., & Hupa, L. (2025). Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors. teoksessa O. Yücel, C. Iloeje, S. Alam, D. P. Guillen, F. Tesfaye, L. Zhang, S. A. C. Hockaday, N. R. Neelameggham, H. Peng, N. Haque, A. A. Baba, T. A. H. Nguyen, A. C. Powell, & D. Zhang (Toimittajat), Energy Technology 2025 - Carbon Dioxide Management and Other Technologies: Carbon Dioxide Management and Other Technologies (1 toim., Vuosikerta 1, Sivut 267-277). (The Minerals, Metals & Materials Series; Vuosikerta 1, Nro 1). Springer, Cham. https://doi.org/10.1007/978-3-031-80688-9_25

Moroz, Mykola ; Demchenko, Pavlo ; Prokhorenko, Myroslava et al. / Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors. Energy Technology 2025 - Carbon Dioxide Management and Other Technologies: Carbon Dioxide Management and Other Technologies. Toimittaja / Onuralp Yücel ; Chukwunwike Iloeje ; Shafiq Alam ; Donna Post Guillen ; Fiseha Tesfaye ; Lei Zhang ; Susanna A. C. Hockaday ; Neale R. Neelameggham ; Hong Peng ; Nawshad Haque ; Alafara Abdullahi Baba ; Tuan A. H. Nguyen ; Adam C. Powell ; Duhan Zhang. Vuosikerta 1 1. toim. Switzerland : Springer, Cham, 2025. Sivut 267-277 (The Minerals, Metals & Materials Series; 1).

@inproceedings{c4b1344f05c14e94b2c94ca9b773fb83,

title = "Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors",

abstract = "In this study, the low-temperature synthesis and thermodynamic propertiesThermodynamic properties of the AgGaGeS 4 compound were analyzed in detail for potential applications in optoelectronicsOptoelectronic compounds and gas sensorsGas sensors. The existence of two four-phase regions Ge–GeS–Ga 2S 3–AgGaGeS 4 and GeS–GeS 2–Ga 2S 3–AgGaGeS 4 in the Ge–GeS 2–Ga 2S 3–AgGaS 2 part of the Ag–Ga–Ge–S system, which are in equilibrium below (540 ± 5) K, has been confirmed through the modified electromotive force (EMF) method. The spatial position of the four-phase regions relative to the silver point was employed to ascertain the overall potential-forming reactions of the AgGaGeS 4 synthesis from mixtures of silver, germanium, and compounds (Ga 2S 3, GeS, GeS 2, AgGaS 2) in the positive electrodes of electrochemical cells. Based on the results obtained, the temperature dependences of the EMF of electrochemical cells were used to determine the values of standard thermodynamic functions (Gibbs energyGibbs energy, enthalpy, and entropy) of the AgGaGeS 4 compound.",

keywords = "Optoelectronic compounds, Gas sensors, Phase equilibria, Thermodynamic properties, EMF method, Gibbs energy",

author = "Mykola Moroz and Pavlo Demchenko and Myroslava Prokhorenko and Bohdan Rudyk and Oleksiy Garashchenko and Serhiy Prokhorenko and Oleksandr Lazarenko and Oleksandr Reshetnyak and Fiseha Tesfaye and Leena Hupa",

year = "2025",

doi = "10.1007/978-3-031-80688-9\_25",

language = "English",

isbn = "978-3-031-80688-9",

volume = "1",

series = "The Minerals, Metals \& Materials Series",

publisher = "Springer, Cham",

number = "1",

pages = "267--277",

editor = "Onuralp Y{\"u}cel and Chukwunwike Iloeje and Shafiq Alam and Guillen, \{Donna Post\} and Fiseha Tesfaye and Lei Zhang and Hockaday, \{Susanna A. C.\} and Neelameggham, \{Neale R.\} and Hong Peng and Nawshad Haque and Baba, \{Alafara Abdullahi\} and Nguyen, \{Tuan A. H.\} and Powell, \{Adam C.\} and Duhan Zhang",

booktitle = "Energy Technology 2025 - Carbon Dioxide Management and Other Technologies",

edition = "1",

}

Moroz, M, Demchenko, P, Prokhorenko, M, Rudyk, B, Garashchenko, O, Prokhorenko, S, Lazarenko, O, Reshetnyak, O, Tesfaye, F & Hupa, L 2025, Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors. julkaisussa O Yücel, C Iloeje, S Alam, DP Guillen, F Tesfaye, L Zhang, SAC Hockaday, NR Neelameggham, H Peng, N Haque, AA Baba, TAH Nguyen, AC Powell & D Zhang (toim), Energy Technology 2025 - Carbon Dioxide Management and Other Technologies: Carbon Dioxide Management and Other Technologies. 1 toim, Vuosikerta 1, The Minerals, Metals & Materials Series, Nro 1, Vuosikerta 1, Springer, Cham, Switzerland, Sivut 267-277. https://doi.org/10.1007/978-3-031-80688-9_25

Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors. / Moroz, Mykola; Demchenko, Pavlo; Prokhorenko, Myroslava et al.
Energy Technology 2025 - Carbon Dioxide Management and Other Technologies: Carbon Dioxide Management and Other Technologies. toim. / Onuralp Yücel; Chukwunwike Iloeje; Shafiq Alam; Donna Post Guillen; Fiseha Tesfaye; Lei Zhang; Susanna A. C. Hockaday; Neale R. Neelameggham; Hong Peng; Nawshad Haque; Alafara Abdullahi Baba; Tuan A. H. Nguyen; Adam C. Powell; Duhan Zhang. Vuosikerta 1 1. toim. Switzerland: Springer, Cham, 2025. s. 267-277 (The Minerals, Metals & Materials Series; Vuosikerta 1, Nro 1).

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussa › Konferenssiartikkeli › Tieteellinen › vertaisarvioitu

TY - GEN

T1 - Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors

AU - Moroz, Mykola

AU - Demchenko, Pavlo

AU - Prokhorenko, Myroslava

AU - Rudyk, Bohdan

AU - Garashchenko, Oleksiy

AU - Prokhorenko, Serhiy

AU - Lazarenko, Oleksandr

AU - Reshetnyak, Oleksandr

AU - Tesfaye, Fiseha

AU - Hupa, Leena

PY - 2025

Y1 - 2025

N2 - In this study, the low-temperature synthesis and thermodynamic propertiesThermodynamic properties of the AgGaGeS 4 compound were analyzed in detail for potential applications in optoelectronicsOptoelectronic compounds and gas sensorsGas sensors. The existence of two four-phase regions Ge–GeS–Ga 2S 3–AgGaGeS 4 and GeS–GeS 2–Ga 2S 3–AgGaGeS 4 in the Ge–GeS 2–Ga 2S 3–AgGaS 2 part of the Ag–Ga–Ge–S system, which are in equilibrium below (540 ± 5) K, has been confirmed through the modified electromotive force (EMF) method. The spatial position of the four-phase regions relative to the silver point was employed to ascertain the overall potential-forming reactions of the AgGaGeS 4 synthesis from mixtures of silver, germanium, and compounds (Ga 2S 3, GeS, GeS 2, AgGaS 2) in the positive electrodes of electrochemical cells. Based on the results obtained, the temperature dependences of the EMF of electrochemical cells were used to determine the values of standard thermodynamic functions (Gibbs energyGibbs energy, enthalpy, and entropy) of the AgGaGeS 4 compound.

AB - In this study, the low-temperature synthesis and thermodynamic propertiesThermodynamic properties of the AgGaGeS 4 compound were analyzed in detail for potential applications in optoelectronicsOptoelectronic compounds and gas sensorsGas sensors. The existence of two four-phase regions Ge–GeS–Ga 2S 3–AgGaGeS 4 and GeS–GeS 2–Ga 2S 3–AgGaGeS 4 in the Ge–GeS 2–Ga 2S 3–AgGaS 2 part of the Ag–Ga–Ge–S system, which are in equilibrium below (540 ± 5) K, has been confirmed through the modified electromotive force (EMF) method. The spatial position of the four-phase regions relative to the silver point was employed to ascertain the overall potential-forming reactions of the AgGaGeS 4 synthesis from mixtures of silver, germanium, and compounds (Ga 2S 3, GeS, GeS 2, AgGaS 2) in the positive electrodes of electrochemical cells. Based on the results obtained, the temperature dependences of the EMF of electrochemical cells were used to determine the values of standard thermodynamic functions (Gibbs energyGibbs energy, enthalpy, and entropy) of the AgGaGeS 4 compound.

KW - Optoelectronic compounds

KW - Gas sensors

KW - Phase equilibria

KW - Thermodynamic properties

KW - EMF method

KW - Gibbs energy

U2 - 10.1007/978-3-031-80688-9_25

DO - 10.1007/978-3-031-80688-9_25

M3 - Published conference proceeding

SN - 978-3-031-80688-9

SN - 978-3-031-80687-2

SN - 978-3-031-80690-2

VL - 1

T3 - The Minerals, Metals & Materials Series

SP - 267

EP - 277

BT - Energy Technology 2025 - Carbon Dioxide Management and Other Technologies

A2 - Yücel, Onuralp

A2 - Iloeje, Chukwunwike

A2 - Alam, Shafiq

A2 - Guillen, Donna Post

A2 - Tesfaye, Fiseha

A2 - Zhang, Lei

A2 - Hockaday, Susanna A. C.

A2 - Neelameggham, Neale R.

A2 - Peng, Hong

A2 - Haque, Nawshad

A2 - Baba, Alafara Abdullahi

A2 - Nguyen, Tuan A. H.

A2 - Powell, Adam C.

A2 - Zhang, Duhan

PB - Springer, Cham

CY - Switzerland

ER -

Moroz M, Demchenko P, Prokhorenko M, Rudyk B, Garashchenko O, Prokhorenko S et al. Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors. julkaisussa Yücel O, Iloeje C, Alam S, Guillen DP, Tesfaye F, Zhang L, Hockaday SAC, Neelameggham NR, Peng H, Haque N, Baba AA, Nguyen TAH, Powell AC, Zhang D, toimittajat, Energy Technology 2025 - Carbon Dioxide Management and Other Technologies: Carbon Dioxide Management and Other Technologies. 1 toim. Vuosikerta 1. Switzerland: Springer, Cham. 2025. s. 267-277. (The Minerals, Metals & Materials Series; 1). doi: 10.1007/978-3-031-80688-9_25

Low-Temperature Synthesis and Thermodynamic Properties of the AgGaGeS4 Compound for Potential Applications in Optoelectronics and Gas Sensors

Abstrakti

Julkaisusarja

Rahoitus

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Sormenjälki

Projektit

GLCE: A step forward on greener and low-carbon extraction and recovery of non-ferrous metals

Aktiviteetit

Energy Technologies and CO2 Management

Viittausmuodot