Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3

Alexey Kirilin; Johan Wärnå; Anton Tokarev; Dmitry Murzin

doi:10.1021/ie403813y

Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3

Alexey Kirilin, Johan Wärnå, Anton Tokarev, Dmitry Murzin

Teknillisen kemian ja reaktiotekniikan laboratorio

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

30 Sitaatiot (Scopus)

Abstrakti

Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C₆-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al₂O₃ catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

Alkuperäiskieli	Ei tiedossa
Sivut	4580–4588
Julkaisu	Industrial & Engineering Chemistry Research
Vuosikerta	53
Numero	12
DOI - pysyväislinkit	https://doi.org/10.1021/ie403813y
Tila	Julkaistu - 2014
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1021/ie403813y

Viittausmuodot

@article{b9006f1c0e1c4a0fa92ecac1cd1480be,

title = "Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3",

abstract = "Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C6-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al2O3 catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.",

author = "Alexey Kirilin and Johan W{\"a}rn{\aa} and Anton Tokarev and Dmitry Murzin",

year = "2014",

doi = "10.1021/ie403813y",

language = "Odefinierat/ok{\"a}nt",

volume = "53",

pages = "4580–4588",

journal = "Industrial & Engineering Chemistry Research",

issn = "0888-5885",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3

AU - Kirilin, Alexey

AU - Wärnå, Johan

AU - Tokarev, Anton

AU - Murzin, Dmitry

PY - 2014

Y1 - 2014

N2 - Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C6-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al2O3 catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

AB - Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C6-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al2O3 catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

U2 - 10.1021/ie403813y

DO - 10.1021/ie403813y

M3 - Artikel

SN - 0888-5885

VL - 53

SP - 4580

EP - 4588

JO - Industrial & Engineering Chemistry Research

JF - Industrial & Engineering Chemistry Research

IS - 12

ER -