Kinetic modeling of one-pot myrtenol amination over Au/ZrO2 catalyst

Yulia Demidova, IL Simakova, Johan Wärnå, A. Simakov, Dmitry Murzin

Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

19 Sitaatiot (Scopus)

Abstrakti

A perspective environmentally-benign one-pot approach to the synthesis of complicated amines by alcohol amination was investigated in this work by mathematical modeling using myrtenol, which represents a natural terpene alcohol, and aniline as model substrates. The reaction was studied in the presence of Au/ZrO2 catalyst in the temperature range 413-453 K under kinetic control. Mechanistic model taking into account catalyst deactivation was developed from a proposed reaction mechanism and corresponding kinetic equations were derived. Kinetic model was compared with experimental data through numerical data fitting showing good correspondence.
AlkuperäiskieliEi tiedossa
Sivut164–171
JulkaisuChemical Engineering Journal
Vuosikerta238
NumeroSpecial issue
DOI - pysyväislinkit
TilaJulkaistu - 2014
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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