Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor

Natalia Bukhanko; Johan Wärnå; Ajaikumar Samikannu; Jyri-Pekka Mikkola

doi:10.1016/j.ces.2015.12.005

Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor

Natalia Bukhanko, Johan Wärnå, Ajaikumar Samikannu, Jyri-Pekka Mikkola

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

3 Sitaatiot (Scopus)

Abstrakti

Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al₂O₃ and 2 wt% ZnCl₂/Al₂O₃ catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

Alkuperäiskieli	Ei tiedossa
Sivut	310–317
Julkaisu	Chemical Engineering Science
Vuosikerta	142
DOI - pysyväislinkit	https://doi.org/10.1016/j.ces.2015.12.005
Tila	Julkaistu - 2016
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1016/j.ces.2015.12.005

http://www.sciencedirect.com/science/article/pii/S0009250915007824

Viittausmuodot

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title = "Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor",

abstract = "Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.",

author = "Natalia Bukhanko and Johan W{\"a}rn{\aa} and Ajaikumar Samikannu and Jyri-Pekka Mikkola",

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year = "2016",

doi = "10.1016/j.ces.2015.12.005",

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volume = "142",

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journal = "Chemical Engineering Science",

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T1 - Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor

AU - Bukhanko, Natalia

AU - Wärnå, Johan

AU - Samikannu, Ajaikumar

AU - Mikkola, Jyri-Pekka

N1 - tk.

PY - 2016

Y1 - 2016

N2 - Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

AB - Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

U2 - 10.1016/j.ces.2015.12.005

DO - 10.1016/j.ces.2015.12.005

M3 - Artikel

SN - 0009-2509

VL - 142

SP - 310

EP - 317

JO - Chemical Engineering Science

JF - Chemical Engineering Science

ER -