Isomerization of α-pinene oxide over ZSM-5 based micro-mesoporous materials

Nataliya D. Shcherban; Roman Yu. Barakov; Päivi Mäki-Arvela; Sergii A. Sergiienko; Igor Bezverkhyy; Kari Eränen; Dmitry Murzin

doi:10.1016/j.apcata.2018.05.007

Isomerization of α-pinene oxide over ZSM-5 based micro-mesoporous materials

Nataliya D. Shcherban, Roman Yu. Barakov, Päivi Mäki-Arvela, Sergii A. Sergiienko, Igor Bezverkhyy, Kari Eränen, Dmitry Murzin

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

32 Sitaatiot (Scopus)

Abstrakti

Few types of ZSM-5 based micro-mesoporous materials obtained via a dual template method, steam-assisted conversion and dual-functional templating were evaluated in α-pinene oxide isomerization. Complete conversion and the highest selectivity towards trans-carveol (ca. 40–43%) were achieved over X-ray amorphous micro-mesoporous aluminosilicates as well as mesoporous molecular sieves AlSi-SBA-15. In addition, X-ray amorphous samples containing the secondary building units of ZSM-5 zeolite demonstrated the highest rate of α-pinene oxide isomerization. The yield of the most desired product trans-carveol to a large extent depends on the accessibility of acid sites to the reagents molecules and acidity of the catalysts (strength and concentration of Brønsted and Lewis acid sites).

Alkuperäiskieli	Ei tiedossa
Sivut	236–247
Julkaisu	Applied Catalysis A: General
Vuosikerta	560
DOI - pysyväislinkit	https://doi.org/10.1016/j.apcata.2018.05.007
Tila	Julkaistu - 2018
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1016/j.apcata.2018.05.007

https://www.sciencedirect.com/science/article/pii/S0926860X18302291

Viittausmuodot

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title = "Isomerization of α-pinene oxide over ZSM-5 based micro-mesoporous materials",

abstract = "Few types of ZSM-5 based micro-mesoporous materials obtained via a dual template method, steam-assisted conversion and dual-functional templating were evaluated in α-pinene oxide isomerization. Complete conversion and the highest selectivity towards trans-carveol (ca. 40–43%) were achieved over X-ray amorphous micro-mesoporous aluminosilicates as well as mesoporous molecular sieves AlSi-SBA-15. In addition, X-ray amorphous samples containing the secondary building units of ZSM-5 zeolite demonstrated the highest rate of α-pinene oxide isomerization. The yield of the most desired product trans-carveol to a large extent depends on the accessibility of acid sites to the reagents molecules and acidity of the catalysts (strength and concentration of Br{\o}nsted and Lewis acid sites).",

author = "Shcherban, {Nataliya D.} and Barakov, {Roman Yu.} and P{\"a}ivi M{\"a}ki-Arvela and Sergiienko, {Sergii A.} and Igor Bezverkhyy and Kari Er{\"a}nen and Dmitry Murzin",

note = "tk. Isomerization of alpha-pinene oxide over ZSM-5 based micro-mesoporous materials",

year = "2018",

doi = "10.1016/j.apcata.2018.05.007",

language = "Odefinierat/ok{\"a}nt",

volume = "560",

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TY - JOUR

T1 - Isomerization of α-pinene oxide over ZSM-5 based micro-mesoporous materials

AU - Shcherban, Nataliya D.

AU - Barakov, Roman Yu.

AU - Mäki-Arvela, Päivi

AU - Sergiienko, Sergii A.

AU - Bezverkhyy, Igor

AU - Eränen, Kari

AU - Murzin, Dmitry

N1 - tk. Isomerization of alpha-pinene oxide over ZSM-5 based micro-mesoporous materials

PY - 2018

Y1 - 2018

N2 - Few types of ZSM-5 based micro-mesoporous materials obtained via a dual template method, steam-assisted conversion and dual-functional templating were evaluated in α-pinene oxide isomerization. Complete conversion and the highest selectivity towards trans-carveol (ca. 40–43%) were achieved over X-ray amorphous micro-mesoporous aluminosilicates as well as mesoporous molecular sieves AlSi-SBA-15. In addition, X-ray amorphous samples containing the secondary building units of ZSM-5 zeolite demonstrated the highest rate of α-pinene oxide isomerization. The yield of the most desired product trans-carveol to a large extent depends on the accessibility of acid sites to the reagents molecules and acidity of the catalysts (strength and concentration of Brønsted and Lewis acid sites).

AB - Few types of ZSM-5 based micro-mesoporous materials obtained via a dual template method, steam-assisted conversion and dual-functional templating were evaluated in α-pinene oxide isomerization. Complete conversion and the highest selectivity towards trans-carveol (ca. 40–43%) were achieved over X-ray amorphous micro-mesoporous aluminosilicates as well as mesoporous molecular sieves AlSi-SBA-15. In addition, X-ray amorphous samples containing the secondary building units of ZSM-5 zeolite demonstrated the highest rate of α-pinene oxide isomerization. The yield of the most desired product trans-carveol to a large extent depends on the accessibility of acid sites to the reagents molecules and acidity of the catalysts (strength and concentration of Brønsted and Lewis acid sites).

U2 - 10.1016/j.apcata.2018.05.007

DO - 10.1016/j.apcata.2018.05.007

M3 - Artikel

SN - 0926-860X

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EP - 247

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

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