Isomerization of α-pinene oxide over iron-modified zeolites

Narendra Kumar; Päivi Mäki-Arvela; Sara Faten Diáz; Atte Aho; Yulia Demidova; Johan Linden; Anna Shepidchenko; Mikko Tenhu; Jarno Salonen; Pekka Laukkanen; Alexander Lashkul; Johnny Dahl; Iliya Sinev; Anne-Riikka Leino; Krisztian Kordas; Tapio Salmi; Dmitry Yu Murzin

doi:10.1007/s11244-013-0029-y

Isomerization of α-pinene oxide over iron-modified zeolites

Narendra Kumar, Päivi Mäki-Arvela, Sara Faten Diáz, Atte Aho, Yulia Demidova, Johan Linden, Anna Shepidchenko, Mikko Tenhu, Jarno Salonen, Pekka Laukkanen, Alexander Lashkul, Johnny Dahl, Iliya Sinev, Anne-Riikka Leino, Krisztian Kordas, Tapio Salmi, Dmitry Yu Murzin^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

37 Sitaatiot (Scopus)

Abstrakti

Fe-modified mordenite, ferrierite, Y, ZSM-5, ZSM-12 and beta zeolite catalysts were prepared by solid state ion-exchange and conventional liquid phase ion-exchange methods from aqueous solutions. Sn- modified H-beta-300 zeolite catalyst was prepared by the later method. The characterization of proton form, Fe and Sn modified zeolites was carried out using X-ray powder diffraction, scanning electron microscopy, Mössbauer spectroscopy with magnetic measurements, transmission electron microscopy, nitrogen adsorption, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, inductively coupled plasma spectroscopy, thermo-gravimetric analysis and FTIR spectroscopy using pyridine as a probe molecule. Isomerization of α-pinene oxide over the Fe and Sn modified zeolite catalysts was carried out in the liquid phase using a batch-wise glass reactor. Formation of campholenic aldehyde and fencholenic aldehyde were observed to be influenced by the structure, acidity of zeolite and contents of Fe and Sn, reaction temperature and the catalysts pretreatment.

Alkuperäiskieli	Englanti
Sivut	696-713
Sivumäärä	18
Julkaisu	Topics in Catalysis
Vuosikerta	56
Numero	9-10
DOI - pysyväislinkit	https://doi.org/10.1007/s11244-013-0029-y
Tila	Julkaistu - huhtik. 2013
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1007/s11244-013-0029-y

Muut tiedostot ja linkit

Link to publication in Scopus

Viittausmuodot

Kumar, N., Mäki-Arvela, P., Diáz, S. F., Aho, A., Demidova, Y., Linden, J., Shepidchenko, A., Tenhu, M., Salonen, J., Laukkanen, P., Lashkul, A., Dahl, J., Sinev, I., Leino, A.-R., Kordas, K., Salmi, T., & Murzin, D. Y. (2013). Isomerization of α-pinene oxide over iron-modified zeolites. Topics in Catalysis, 56(9-10), 696-713. https://doi.org/10.1007/s11244-013-0029-y

@article{dd24009df7c7412bb897ee7313fba1cd,

title = "Isomerization of α-pinene oxide over iron-modified zeolites",

abstract = "Fe-modified mordenite, ferrierite, Y, ZSM-5, ZSM-12 and beta zeolite catalysts were prepared by solid state ion-exchange and conventional liquid phase ion-exchange methods from aqueous solutions. Sn- modified H-beta-300 zeolite catalyst was prepared by the later method. The characterization of proton form, Fe and Sn modified zeolites was carried out using X-ray powder diffraction, scanning electron microscopy, M{\"o}ssbauer spectroscopy with magnetic measurements, transmission electron microscopy, nitrogen adsorption, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, inductively coupled plasma spectroscopy, thermo-gravimetric analysis and FTIR spectroscopy using pyridine as a probe molecule. Isomerization of α-pinene oxide over the Fe and Sn modified zeolite catalysts was carried out in the liquid phase using a batch-wise glass reactor. Formation of campholenic aldehyde and fencholenic aldehyde were observed to be influenced by the structure, acidity of zeolite and contents of Fe and Sn, reaction temperature and the catalysts pretreatment.",

keywords = "α-Pinene oxide, Campholenic aldehyde, Fe, Isomerization, Sn, Zeolites",

author = "Narendra Kumar and P{\"a}ivi M{\"a}ki-Arvela and Di{\'a}z, {Sara Faten} and Atte Aho and Yulia Demidova and Johan Linden and Anna Shepidchenko and Mikko Tenhu and Jarno Salonen and Pekka Laukkanen and Alexander Lashkul and Johnny Dahl and Iliya Sinev and Anne-Riikka Leino and Krisztian Kordas and Tapio Salmi and Murzin, {Dmitry Yu}",

year = "2013",

month = apr,

doi = "10.1007/s11244-013-0029-y",

language = "English",

volume = "56",

pages = "696--713",

journal = "Topics in Catalysis",

issn = "1022-5528",

publisher = "Springer",

number = "9-10",

}

Kumar, N , Mäki-Arvela, P, Diáz, SF, Aho, A, Demidova, Y, Linden, J, Shepidchenko, A, Tenhu, M, Salonen, J, Laukkanen, P, Lashkul, A, Dahl, J, Sinev, I, Leino, A-R, Kordas, K, Salmi, T & Murzin, DY 2013, 'Isomerization of α-pinene oxide over iron-modified zeolites', Topics in Catalysis, Vuosikerta 56, Nro 9-10, Sivut 696-713. https://doi.org/10.1007/s11244-013-0029-y

TY - JOUR

T1 - Isomerization of α-pinene oxide over iron-modified zeolites

AU - Kumar, Narendra

AU - Mäki-Arvela, Päivi

AU - Diáz, Sara Faten

AU - Aho, Atte

AU - Demidova, Yulia

AU - Linden, Johan

AU - Shepidchenko, Anna

AU - Tenhu, Mikko

AU - Salonen, Jarno

AU - Laukkanen, Pekka

AU - Lashkul, Alexander

AU - Dahl, Johnny

AU - Sinev, Iliya

AU - Leino, Anne-Riikka

AU - Kordas, Krisztian

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

PY - 2013/4

Y1 - 2013/4

N2 - Fe-modified mordenite, ferrierite, Y, ZSM-5, ZSM-12 and beta zeolite catalysts were prepared by solid state ion-exchange and conventional liquid phase ion-exchange methods from aqueous solutions. Sn- modified H-beta-300 zeolite catalyst was prepared by the later method. The characterization of proton form, Fe and Sn modified zeolites was carried out using X-ray powder diffraction, scanning electron microscopy, Mössbauer spectroscopy with magnetic measurements, transmission electron microscopy, nitrogen adsorption, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, inductively coupled plasma spectroscopy, thermo-gravimetric analysis and FTIR spectroscopy using pyridine as a probe molecule. Isomerization of α-pinene oxide over the Fe and Sn modified zeolite catalysts was carried out in the liquid phase using a batch-wise glass reactor. Formation of campholenic aldehyde and fencholenic aldehyde were observed to be influenced by the structure, acidity of zeolite and contents of Fe and Sn, reaction temperature and the catalysts pretreatment.

AB - Fe-modified mordenite, ferrierite, Y, ZSM-5, ZSM-12 and beta zeolite catalysts were prepared by solid state ion-exchange and conventional liquid phase ion-exchange methods from aqueous solutions. Sn- modified H-beta-300 zeolite catalyst was prepared by the later method. The characterization of proton form, Fe and Sn modified zeolites was carried out using X-ray powder diffraction, scanning electron microscopy, Mössbauer spectroscopy with magnetic measurements, transmission electron microscopy, nitrogen adsorption, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, inductively coupled plasma spectroscopy, thermo-gravimetric analysis and FTIR spectroscopy using pyridine as a probe molecule. Isomerization of α-pinene oxide over the Fe and Sn modified zeolite catalysts was carried out in the liquid phase using a batch-wise glass reactor. Formation of campholenic aldehyde and fencholenic aldehyde were observed to be influenced by the structure, acidity of zeolite and contents of Fe and Sn, reaction temperature and the catalysts pretreatment.

KW - α-Pinene oxide

KW - Campholenic aldehyde

KW - Fe

KW - Isomerization

KW - Sn

KW - Zeolites

UR - http://www.scopus.com/inward/record.url?scp=84879847517&partnerID=8YFLogxK

U2 - 10.1007/s11244-013-0029-y

DO - 10.1007/s11244-013-0029-y

M3 - Article

AN - SCOPUS:84879847517

SN - 1022-5528

VL - 56

SP - 696

EP - 713

JO - Topics in Catalysis

JF - Topics in Catalysis

IS - 9-10

ER -

Isomerization of α-pinene oxide over iron-modified zeolites

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