Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

Ewelina Leino; Narendra Kumar; Päivi Mäki-Arvela; Atte Aho; Krisztián Kordás; Anne-Riikka Leino; Andrey Shchukarev; Dmitry Yu Murzin; Jyri Pekka Mikkola

doi:10.1016/j.matchemphys.2013.08.012

Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

Ewelina Leino
, Narendra Kumar
, Päivi Mäki-Arvela
, Atte Aho
, Krisztián Kordás
, Anne-Riikka Leino
, Andrey Shchukarev
, Dmitry Yu Murzin^*
, Jyri Pekka Mikkola

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

33 Sitaatiot (Scopus)

Abstrakti

Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO ₂ properties was discussed. Moreover, the comparison of CeO ₂ samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO₂. Significant variations in physico-chemical properties of CeO₂ by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO ₂ catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO₂ using butylene oxide as a dehydrating agent. The dependence of CeO₂ properties on its catalytic activity is evaluated in detail.

Alkuperäiskieli	Englanti
Sivut	65-75
Sivumäärä	11
Julkaisu	Materials Chemistry and Physics
Vuosikerta	143
Numero	1
DOI - pysyväislinkit	https://doi.org/10.1016/j.matchemphys.2013.08.012
Tila	Julkaistu - 16 jouluk. 2013
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Rahoitus

This work is part of the activities at the Åbo Akademi Process Chemistry Centre (ÅA-PCC) within the Finnish Centre of Excellence Programme appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Umeå University Technical Chemistry whereupon financial support from Bio4Energy programme , Kempe and Knut & Alice Wallenberg Foundations is acknowledged.

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10.1016/j.matchemphys.2013.08.012

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Leino, E., Kumar, N., Mäki-Arvela, P., Aho, A., Kordás, K., Leino, A.-R., Shchukarev, A., Murzin, D. Y., & Mikkola, J. P. (2013). Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate. Materials Chemistry and Physics, 143(1), 65-75. https://doi.org/10.1016/j.matchemphys.2013.08.012

@article{b3189b20848c4579b5c92951162646d5,

title = "Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate",

abstract = "Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO 2 properties was discussed. Moreover, the comparison of CeO 2 samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO2. Significant variations in physico-chemical properties of CeO2 by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO 2 catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO2 using butylene oxide as a dehydrating agent. The dependence of CeO2 properties on its catalytic activity is evaluated in detail.",

keywords = "Inorganic compounds, Oxides, Photoelectron spectroscopy, Surface properties",

author = "Ewelina Leino and Narendra Kumar and P{\"a}ivi M{\"a}ki-Arvela and Atte Aho and Kriszti{\'a}n Kord{\'a}s and Anne-Riikka Leino and Andrey Shchukarev and Murzin, \{Dmitry Yu\} and Mikkola, \{Jyri Pekka\}",

note = "Funding Information: This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre ({\AA}A-PCC) within the Finnish Centre of Excellence Programme appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Ume{\aa} University Technical Chemistry whereupon financial support from Bio4Energy programme , Kempe and Knut \& Alice Wallenberg Foundations is acknowledged. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.",

year = "2013",

month = dec,

day = "16",

doi = "10.1016/j.matchemphys.2013.08.012",

language = "English",

volume = "143",

pages = "65--75",

journal = "Materials Chemistry and Physics",

issn = "0254-0584",

publisher = "Elsevier",

number = "1",

}

Leino, E, Kumar, N , Mäki-Arvela, P , Aho, A, Kordás, K, Leino, A-R, Shchukarev, A, Murzin, DY & Mikkola, JP 2013, 'Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate', Materials Chemistry and Physics, Vuosikerta 143, Nro 1, Sivut 65-75. https://doi.org/10.1016/j.matchemphys.2013.08.012

Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate. / Leino, Ewelina; Kumar, Narendra ; Mäki-Arvela, Päivi et al.
julkaisussa: Materials Chemistry and Physics, Vuosikerta 143, Nro 1, 16.12.2013, s. 65-75.

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

TY - JOUR

T1 - Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

AU - Leino, Ewelina

AU - Kumar, Narendra

AU - Mäki-Arvela, Päivi

AU - Aho, Atte

AU - Kordás, Krisztián

AU - Leino, Anne-Riikka

AU - Shchukarev, Andrey

AU - Murzin, Dmitry Yu

AU - Mikkola, Jyri Pekka

N1 - Funding Information: This work is part of the activities at the Åbo Akademi Process Chemistry Centre (ÅA-PCC) within the Finnish Centre of Excellence Programme appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Umeå University Technical Chemistry whereupon financial support from Bio4Energy programme , Kempe and Knut & Alice Wallenberg Foundations is acknowledged. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.

PY - 2013/12/16

Y1 - 2013/12/16

N2 - Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO 2 properties was discussed. Moreover, the comparison of CeO 2 samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO2. Significant variations in physico-chemical properties of CeO2 by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO 2 catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO2 using butylene oxide as a dehydrating agent. The dependence of CeO2 properties on its catalytic activity is evaluated in detail.

AB - Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO 2 properties was discussed. Moreover, the comparison of CeO 2 samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO2. Significant variations in physico-chemical properties of CeO2 by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO 2 catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO2 using butylene oxide as a dehydrating agent. The dependence of CeO2 properties on its catalytic activity is evaluated in detail.

KW - Inorganic compounds

KW - Oxides

KW - Photoelectron spectroscopy

KW - Surface properties

UR - https://www.scopus.com/pages/publications/84886719516

U2 - 10.1016/j.matchemphys.2013.08.012

DO - 10.1016/j.matchemphys.2013.08.012

M3 - Article

AN - SCOPUS:84886719516

SN - 0254-0584

VL - 143

SP - 65

EP - 75

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

IS - 1

ER -

Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

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