Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

Reko Leino; Luttikhedde HJG; L Langstedt; A Penninkangas

Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

Reko Leino, Luttikhedde HJG, L Langstedt, A Penninkangas

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

5 Sitaatiot (Scopus)

Abstrakti

The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.

Alkuperäiskieli	Ei tiedossa
Sivut	4149–4151
Sivumäärä	3
Julkaisu	Tetrahedron Letters
Vuosikerta	43
Numero	23
Tila	Julkaistu - 2002
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Viittausmuodot

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title = "Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes",

abstract = "The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.",

author = "Reko Leino and Luttikhedde HJG and L Langstedt and A Penninkangas",

year = "2002",

language = "Odefinierat/ok{\"a}nt",

volume = "43",

pages = "4149–4151",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "23",

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TY - JOUR

T1 - Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

AU - Leino, Reko

AU - HJG, Luttikhedde

AU - Langstedt, L

AU - Penninkangas, A

PY - 2002

Y1 - 2002

N2 - The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.

M3 - Artikel

SN - 0040-4039

VL - 43

SP - 4149

EP - 4151

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 23

ER -