Hydrocracking of hexadecane to jet fuel components over hierarchical Ru-modified faujasite zeolite

Muhammad Azkaar; Zuzana Vajglová; Päivi Mäki-Arvela; Atte Aho; Narendra Kumar; Heikki Palonen; Kari Eränen; Markus Peurla; Leonid A. Kulikov; Anton L. Maximov; Cecilia Mondelli; Javier Pérez-Ramírez; Dmitry Yu Murzin

doi:10.1016/j.fuel.2020.118193

Hydrocracking of hexadecane to jet fuel components over hierarchical Ru-modified faujasite zeolite

Muhammad Azkaar, Zuzana Vajglová, Päivi Mäki-Arvela, Atte Aho, Narendra Kumar, Heikki Palonen, Kari Eränen, Markus Peurla, Leonid A. Kulikov, Anton L. Maximov, Cecilia Mondelli, Javier Pérez-Ramírez, Dmitry Yu Murzin^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

25 Sitaatiot (Scopus)

92 Lataukset (Pure)

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Hexadecane hydrocracking was investigated over bifunctional Ru-containing micro- and mesoporous USY zeolites at 250°C under 45 bar in the presence of hydrogen in a batch reactor. A comparative study was performed using the Ru-free zeolites in the protonic form. The highest yield of jet-fuel products, C₉ - C₁₅, being 26% at 71% conversion, was obtained with 2.5 wt% Ru deposited on a hierarchical micro-mesoporous USY zeolite, e.g. a material possessing secondary porosity, where a superior combination of acidity and mesoporosity was created by treatment of the parent zeolite with aqueous sodium hydroxide and tetrapropylammonium hydroxide.

Alkuperäiskieli	Englanti
Artikkeli	118193
Julkaisu	Fuel
Vuosikerta	278
DOI - pysyväislinkit	https://doi.org/10.1016/j.fuel.2020.118193
Tila	Julkaistu - 15 lokak. 2020
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

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10.1016/j.fuel.2020.118193

Hydrocracking of hexadecane to jet fuel components over hierarchical Ru-modified faujasite zeoliteHyväksytty kirjoittajan käsikirjoitus, 3,93 MBLisenssi: CC BY-NC-ND

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@article{82b691179b844c9cb89adbbdf3f3b86d,

title = "Hydrocracking of hexadecane to jet fuel components over hierarchical Ru-modified faujasite zeolite",

abstract = "Hexadecane hydrocracking was investigated over bifunctional Ru-containing micro- and mesoporous USY zeolites at 250°C under 45 bar in the presence of hydrogen in a batch reactor. A comparative study was performed using the Ru-free zeolites in the protonic form. The highest yield of jet-fuel products, C9 - C15, being 26% at 71% conversion, was obtained with 2.5 wt% Ru deposited on a hierarchical micro-mesoporous USY zeolite, e.g. a material possessing secondary porosity, where a superior combination of acidity and mesoporosity was created by treatment of the parent zeolite with aqueous sodium hydroxide and tetrapropylammonium hydroxide.",

keywords = "Hexadecane, Hierarchical zeolite, Hydrocracking, Ruthenium",

author = "Muhammad Azkaar and Zuzana Vajglov{\'a} and P{\"a}ivi M{\"a}ki-Arvela and Atte Aho and Narendra Kumar and Heikki Palonen and Kari Er{\"a}nen and Markus Peurla and Kulikov, {Leonid A.} and Maximov, {Anton L.} and Cecilia Mondelli and Javier P{\'e}rez-Ram{\'i}rez and Murzin, {Dmitry Yu}",

note = "Muhammad Azkaar is affiliated with {\AA}AU. [Har kontaktat Babo 23.11.2020 LN] post-print, 24 m{\aa}n embargo CC-BY-NC-ND [Har mailat Murzin 23.11.2020 LN] ",

year = "2020",

month = oct,

day = "15",

doi = "10.1016/j.fuel.2020.118193",

language = "English",

volume = "278",

journal = "Fuel",

issn = "0016-2361",

publisher = "Elsevier",

}

TY - JOUR

T1 - Hydrocracking of hexadecane to jet fuel components over hierarchical Ru-modified faujasite zeolite

AU - Azkaar, Muhammad

AU - Vajglová, Zuzana

AU - Mäki-Arvela, Päivi

AU - Aho, Atte

AU - Kumar, Narendra

AU - Palonen, Heikki

AU - Eränen, Kari

AU - Peurla, Markus

AU - Kulikov, Leonid A.

AU - Maximov, Anton L.

AU - Mondelli, Cecilia

AU - Pérez-Ramírez, Javier

AU - Murzin, Dmitry Yu

N1 - Muhammad Azkaar is affiliated with ÅAU. [Har kontaktat Babo 23.11.2020 LN] post-print, 24 mån embargo CC-BY-NC-ND [Har mailat Murzin 23.11.2020 LN]

PY - 2020/10/15

Y1 - 2020/10/15

N2 - Hexadecane hydrocracking was investigated over bifunctional Ru-containing micro- and mesoporous USY zeolites at 250°C under 45 bar in the presence of hydrogen in a batch reactor. A comparative study was performed using the Ru-free zeolites in the protonic form. The highest yield of jet-fuel products, C9 - C15, being 26% at 71% conversion, was obtained with 2.5 wt% Ru deposited on a hierarchical micro-mesoporous USY zeolite, e.g. a material possessing secondary porosity, where a superior combination of acidity and mesoporosity was created by treatment of the parent zeolite with aqueous sodium hydroxide and tetrapropylammonium hydroxide.

AB - Hexadecane hydrocracking was investigated over bifunctional Ru-containing micro- and mesoporous USY zeolites at 250°C under 45 bar in the presence of hydrogen in a batch reactor. A comparative study was performed using the Ru-free zeolites in the protonic form. The highest yield of jet-fuel products, C9 - C15, being 26% at 71% conversion, was obtained with 2.5 wt% Ru deposited on a hierarchical micro-mesoporous USY zeolite, e.g. a material possessing secondary porosity, where a superior combination of acidity and mesoporosity was created by treatment of the parent zeolite with aqueous sodium hydroxide and tetrapropylammonium hydroxide.

KW - Hexadecane

KW - Hierarchical zeolite

KW - Hydrocracking

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=85086874050&partnerID=8YFLogxK

U2 - 10.1016/j.fuel.2020.118193

DO - 10.1016/j.fuel.2020.118193

M3 - Article

AN - SCOPUS:85086874050

SN - 0016-2361

VL - 278

JO - Fuel

JF - Fuel

M1 - 118193

ER -

Hydrocracking of hexadecane to jet fuel components over hierarchical Ru-modified faujasite zeolite

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