Heteroatom-substituted group 4 bis(indenyl)metallocenes

Reko Leino, P Lehmus, A Lehtonen

    Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

    92 Sitaatiot (Scopus)

    Abstrakti

    The synthesis, characterization and applications of heteroatom-substituted group 4 bis(indenyl)metallocene complexes is reviewed. In recent years, an increasing number of group 4 metallocenes with electronically modified cyclopentadienyl ligands have been reported with, in some cases, considerably altered catalytic properties. This microreview focuses on bis(indenyl) complexes of titanium, zirconium and hafnium that contain nitrogen, oxygen and sulfur atoms directly bonded to the five- or six-membered rings of the indenyl ligand framework. The catalytic performance is briefly reviewed, with emphasis on catalytic olefin polymerization. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
    AlkuperäiskieliEi tiedossa
    Sivut3201–3222
    Sivumäärä22
    JulkaisuEuropean Journal of Inorganic Chemistry
    Vuosikerta2004
    Numero16
    DOI - pysyväislinkit
    TilaJulkaistu - 2004
    OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

    Keywords

    • indene
    • metallocenes
    • olefin polymerization
    • zirconium

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