Heat optimisation of a staged gas-solid mineral carbonation process for long-term CO2 storage

Ron Zevenhoven*, Sebastian Teir, Sanni Eloneva

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussaKonferenssiartikkeliTieteellinenvertaisarvioitu

2 Sitaatiot (Scopus)

Abstrakti

The carbonation of silicate minerals, primarily magnesium silicates, offers an interesting CO2 emissions mitigation option for Finland. Despite large resources of serpentine-type mineral in Finland and at many other places worldwide (exceeding the amount needed to bind the earth's fossil carbon resources) the chemical processing leaves much to be improved. Important features are the very slow chemical kinetics of magnesium silicate carbonation and the fact that the overall carbonation reaction is exothermic. Currently, two carbonation routes can be distinguished: Wet processes using aqueous solutions that give reasonable chemical kinetics while suffering from bad energy economy, and dry, gas-solid processes for which less good chemical kinetics have been achieved so far, but with better energy economy characteristics. The energy economy of a two- or three-stage gas-solid process for magnesium silicate is addressed in this paper. This involves extraction of reactive magnesium as magnesium oxide or hydroxide in an atmospheric pressure step, followed by carbonation at a higher temperature (>500°C) and at elevated pressures (>20 bar) that allow for reasonable carbonation reaction kinetics under conditions where magnesium carbonate is thermodynamically stable. Two goals must be achieved at the same time in a process that is feasible for large-scale application: The kinetics in the individual reactors must be fast enough, and the heat produced in the carbonation step must be sufficient to compensate for energy inputs to the preceding step(s). Excess heat will be of such a temperature level that it may be used in a steam cycle to produce electricity. The results of the paper show what temperature combinations will allow for operation at a negative or zero energy input, for a given pressure of the carbonation process step, given a degree of carbonation conversion and given other energy inputs, such as for mineral preparation and CO2 pre-heat. Softwares used were HSC and Aspen Plus. Also, a few results from gas-solid kinetics studies with magnesium oxidebased materials at the elevated pressures considered are included.

AlkuperäiskieliEnglanti
OtsikkoECOS 2006 - Proceedings of the 19th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems
ToimittajatChristos A. Frangopoulos, Constantine D. Rakopoulos, George Tsatsaronis
KustantajaNational Technical University of Athens
Sivut1661-1669
Sivumäärä9
ISBN (elektroninen)9608758424
TilaJulkaistu - 2006
OKM-julkaisutyyppiA4 Artikkeli konferenssijulkaisuussa
Tapahtuma19th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, ECOS 2006 - Aghia Pelagia, Crete, Greece
Kesto: 12 heinäkuuta 200614 heinäkuuta 2006

Julkaisusarja

NimiECOS 2006 - Proceedings of the 19th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems

Konferenssi

Konferenssi19th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, ECOS 2006
Maa/AlueGreece
KaupunkiAghia Pelagia, Crete
Ajanjakso12/07/0614/07/06

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