@inproceedings{6d548464a0bb426794fb19f6f04d5244,
title = "Experimental thermodynamic study on the Ag-Sb system at elevated temperatures",
abstract = "In this paper, the standard thermodynamic properties of Ag3Sb and Ag6Sb intermetallic compounds have been studied by the solid state EMF-method, using Ag+ ion conducting β- Alumina and Ag+. The intermetallic compounds were synthesized from pure substances in evacuated silica ampoules and their formation were confirmed by the SEM-EDS analyses. The EMF measurements were made on electrochemical cells of the type [Ag | β-alumina | Ag-Sb] and [Ag | Agl | Ag-Sb], The usage of β-alumina electrolyte, in this study, enabled thermodynamic measurements of the Ag-Sb-intermetallic compounds above 710 K, hitherto unreported. Based on the new experimental data, thermodynamic properties of the Ag-Sb-intermetallic compounds have been determined. The obtained experimental values have been compared with the available literature data.",
keywords = "AgSb, Electrochemistry, Emf technique, Gibbs energy of formation",
author = "Markus Aspiala and Fiseha Tesfaye and Pekka Taskinen",
note = "This work was published when I was working for Aalto University.; EPD Congress 2015 - TMS 2015 144th Annual Meeting and Exhibition ; Conference date: 15-03-2015 Through 19-03-2015",
year = "2015",
doi = "10.1002/9781119093503.ch35",
language = "English",
isbn = "9781119082453",
series = "TMS Annual Meeting",
publisher = "Minerals, metals and materials society",
number = "January",
pages = "305--312",
editor = "Yurko, \{James A.\} and Yurko, \{James A.\} and Antoine Allanore and Laura Bartlett and Laura Bartlett and Jonghyun Lee and Lifeng Zhang and Gabriella Tranell and Yulia Meteleva-Fischer and Shadia Ikhmayies and Shadia Ikhmayies and Budiman, \{Arief Suriadi\} and Prabhat Tripathy and Fredrickson, \{Guy Lawrence\}",
booktitle = "EPD Congress 2015 - Held During TMS 2015 144th Annual Meeting and Exhibition",
address = "United States",
edition = "January",
}