Experimental thermodynamic study on the Ag-Sb system at elevated temperatures

Markus Aspiala, Fiseha Tesfaye, Pekka Taskinen

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussaKonferenssiartikkeliTieteellinenvertaisarvioitu

Abstrakti

In this paper, the standard thermodynamic properties of Ag3Sb and Ag6Sb intermetallic compounds have been studied by the solid state EMF-method, using Ag+ ion conducting β- Alumina and Ag+. The intermetallic compounds were synthesized from pure substances in evacuated silica ampoules and their formation were confirmed by the SEM-EDS analyses. The EMF measurements were made on electrochemical cells of the type [Ag | β-alumina | Ag-Sb] and [Ag | Agl | Ag-Sb], The usage of β-alumina electrolyte, in this study, enabled thermodynamic measurements of the Ag-Sb-intermetallic compounds above 710 K, hitherto unreported. Based on the new experimental data, thermodynamic properties of the Ag-Sb-intermetallic compounds have been determined. The obtained experimental values have been compared with the available literature data.

AlkuperäiskieliEnglanti
OtsikkoEPD Congress 2015 - Held During TMS 2015 144th Annual Meeting and Exhibition
ToimittajatJames A. Yurko, James A. Yurko, Antoine Allanore, Laura Bartlett, Laura Bartlett, Jonghyun Lee, Lifeng Zhang, Lifeng Zhang, Lifeng Zhang, Gabriella Tranell, Yulia Meteleva-Fischer, Shadia Ikhmayies, Shadia Ikhmayies, Arief Suriadi Budiman, Prabhat Tripathy, Guy Lawrence Fredrickson
KustantajaMinerals, metals and materials society
Sivut305-312
Sivumäärä8
PainosJanuary
ISBN (elektroninen)9781119082453
DOI - pysyväislinkit
TilaJulkaistu - 2015
OKM-julkaisutyyppiA4 Artikkeli konferenssijulkaisuussa
TapahtumaEPD Congress 2015 - TMS 2015 144th Annual Meeting and Exhibition - Orlando, United States
Kesto: 15 maaliskuuta 201519 maaliskuuta 2015

Julkaisusarja

NimiTMS Annual Meeting
NumeroJanuary
Vuosikerta2015-January

Konferenssi

KonferenssiEPD Congress 2015 - TMS 2015 144th Annual Meeting and Exhibition
Maa/AlueUnited States
KaupunkiOrlando
Ajanjakso15/03/1519/03/15

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