Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

Serap Sahin; Päivi Mäki-Arvela; Jean Philippe Tessonnier; Alberto Villa; Lidong Shao; Dang Sheng Su; Robert Schlögl; Tapio Salmi; Dmitry Yu Murzin

doi:10.1016/S0167-2991(10)75043-6

Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

Serap Sahin^*, Päivi Mäki-Arvela, Jean Philippe Tessonnier, Alberto Villa, Lidong Shao, Dang Sheng Su, Robert Schlögl, Tapio Salmi, Dmitry Yu Murzin

^*Tämän työn vastaava kirjoittaja

Industrial Chemistry and Reaction Engineering

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussa › Konferenssiartikkeli › Tieteellinen › vertaisarvioitu

4 Sitaatiot (Scopus)

Abstrakti

Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH₃ at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.

Alkuperäiskieli	Englanti
Otsikko	Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium
Kustantaja	Elsevier
Sivut	283-287
Sivumäärä	5
ISBN (painettu)	9780444536013
DOI - pysyväislinkit	https://doi.org/10.1016/S0167-2991(10)75043-6
Tila	Julkaistu - 2010
OKM-julkaisutyyppi	A4 Artikkeli konferenssijulkaisuussa

Julkaisusarja

Nimi	Studies in Surface Science and Catalysis
Vuosikerta	175
ISSN (painettu)	0167-2991

Pääsy asiakirjaan

10.1016/S0167-2991(10)75043-6

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Sahin, S., Mäki-Arvela, P., Tessonnier, J. P., Villa, A., Shao, L., Su, D. S., Schlögl, R., Salmi, T., & Murzin, D. Y. (2010). Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. teoksessa Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium (Sivut 283-287). (Studies in Surface Science and Catalysis; Vuosikerta 175). Elsevier. https://doi.org/10.1016/S0167-2991(10)75043-6

@inproceedings{bc288ba403614d569cbcce4cafd06a5b,

title = "Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate",

abstract = "Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH3 at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.",

keywords = "Acetophenone, Carbon nanotubes, Immobilized lipase, One-pot cascades",

author = "Serap Sahin and P{\"a}ivi M{\"a}ki-Arvela and Tessonnier, {Jean Philippe} and Alberto Villa and Lidong Shao and Su, {Dang Sheng} and Robert Schl{\"o}gl and Tapio Salmi and Murzin, {Dmitry Yu}",

year = "2010",

doi = "10.1016/S0167-2991(10)75043-6",

language = "English",

isbn = "9780444536013",

series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier",

pages = "283--287",

booktitle = "Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium",

}

Sahin, S, Mäki-Arvela, P, Tessonnier, JP, Villa, A, Shao, L, Su, DS, Schlögl, R, Salmi, T & Murzin, DY 2010, Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. julkaisussa Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium. Studies in Surface Science and Catalysis, Vuosikerta 175, Elsevier, Sivut 283-287. https://doi.org/10.1016/S0167-2991(10)75043-6

Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. / Sahin, Serap; Mäki-Arvela, Päivi; Tessonnier, Jean Philippe et al.
Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium. Elsevier, 2010. s. 283-287 (Studies in Surface Science and Catalysis; Vuosikerta 175).

Tutkimustuotos: Artikkeli kirjassa/raportissa/konferenssijulkaisussa › Konferenssiartikkeli › Tieteellinen › vertaisarvioitu

TY - GEN

T1 - Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

AU - Sahin, Serap

AU - Mäki-Arvela, Päivi

AU - Tessonnier, Jean Philippe

AU - Villa, Alberto

AU - Shao, Lidong

AU - Su, Dang Sheng

AU - Schlögl, Robert

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

PY - 2010

Y1 - 2010

N2 - Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH3 at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.

AB - Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH3 at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.

KW - Acetophenone

KW - Carbon nanotubes

KW - Immobilized lipase

KW - One-pot cascades

UR - http://www.scopus.com/inward/record.url?scp=79551616367&partnerID=8YFLogxK

U2 - 10.1016/S0167-2991(10)75043-6

DO - 10.1016/S0167-2991(10)75043-6

M3 - Conference contribution

AN - SCOPUS:79551616367

SN - 9780444536013

T3 - Studies in Surface Science and Catalysis

SP - 283

EP - 287

BT - Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium

PB - Elsevier

ER -

Sahin S, Mäki-Arvela P, Tessonnier JP, Villa A, Shao L, Su DS et al. Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. julkaisussa Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium. Elsevier. 2010. s. 283-287. (Studies in Surface Science and Catalysis). doi: 10.1016/S0167-2991(10)75043-6

Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

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