Effect of modifier structure in the enantioselective hydrogenation of 1-phenyl-1,2-propanedione

E Toukoniitty; Päivi Mäki-Arvela; R Sjoholm; Reko Leino; T Salmi; Dmitry Murzin

Effect of modifier structure in the enantioselective hydrogenation of 1-phenyl-1,2-propanedione

E Toukoniitty
, Päivi Mäki-Arvela
, R Sjoholm
, Reko Leino
, T Salmi
, Dmitry Murzin

Teknillisen kemian ja reaktiotekniikan laboratorio

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

16 Sitaatiot (Scopus)

Abstrakti

Three different modifiers, (-)-cinchonidine, 10,11-dihydrocinchonidine and (+)-cinchonine were investigated in the enantioselective hydrogenation of an unsymmetrical dione, 1-phenyl-1,2-propanedione, over a commercial Pt/Al(2)O(3) catalyst. The catalytic activity, as well as the regio- and enantioselectivity in the hydroxyketones and diols formed were compared.

Alkuperäiskieli	Ei tiedossa
Sivut	21–30
Sivumäärä	10
Julkaisu	Reaction Kinetics and Catalysis Letters
Vuosikerta	75
Numero	1
Tila	Julkaistu - 2002
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Keywords

chiral modifier
dione
enantioselective hydrogenation

Viittausmuodot

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title = "Effect of modifier structure in the enantioselective hydrogenation of 1-phenyl-1,2-propanedione",

abstract = "Three different modifiers, (-)-cinchonidine, 10,11-dihydrocinchonidine and (+)-cinchonine were investigated in the enantioselective hydrogenation of an unsymmetrical dione, 1-phenyl-1,2-propanedione, over a commercial Pt/Al(2)O(3) catalyst. The catalytic activity, as well as the regio- and enantioselectivity in the hydroxyketones and diols formed were compared.",

keywords = "chiral modifier, dione, enantioselective hydrogenation, chiral modifier, dione, enantioselective hydrogenation, chiral modifier, dione, enantioselective hydrogenation",

author = "E Toukoniitty and P{\"a}ivi M{\"a}ki-Arvela and R Sjoholm and Reko Leino and T Salmi and Dmitry Murzin",

year = "2002",

language = "Odefinierat/ok{\"a}nt",

volume = "75",

pages = "21–30",

journal = "Reaction Kinetics and Catalysis Letters",

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TY - JOUR

T1 - Effect of modifier structure in the enantioselective hydrogenation of 1-phenyl-1,2-propanedione

AU - Toukoniitty, E

AU - Mäki-Arvela, Päivi

AU - Sjoholm, R

AU - Leino, Reko

AU - Salmi, T

AU - Murzin, Dmitry

PY - 2002

Y1 - 2002

N2 - Three different modifiers, (-)-cinchonidine, 10,11-dihydrocinchonidine and (+)-cinchonine were investigated in the enantioselective hydrogenation of an unsymmetrical dione, 1-phenyl-1,2-propanedione, over a commercial Pt/Al(2)O(3) catalyst. The catalytic activity, as well as the regio- and enantioselectivity in the hydroxyketones and diols formed were compared.

AB - Three different modifiers, (-)-cinchonidine, 10,11-dihydrocinchonidine and (+)-cinchonine were investigated in the enantioselective hydrogenation of an unsymmetrical dione, 1-phenyl-1,2-propanedione, over a commercial Pt/Al(2)O(3) catalyst. The catalytic activity, as well as the regio- and enantioselectivity in the hydroxyketones and diols formed were compared.

KW - chiral modifier

KW - dione

KW - enantioselective hydrogenation

KW - chiral modifier

KW - dione

KW - enantioselective hydrogenation

KW - chiral modifier

KW - dione

KW - enantioselective hydrogenation

M3 - Artikel

SN - 0133-1736

VL - 75

SP - 21

EP - 30

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 1

ER -