Abstrakti
Fatty acid decarboxylation was studied in a semibatch reactor over 1 wt.% Pd/C (Sibunit) using five different fatty acids, C17-C20 and C22, as feeds. The same decarboxylation rates were obtained for pure fatty acids, whereas extensive catalyst poisoning and/or sintering and coking occurred with low purity fatty acids as reactants. One reason for catalyst poisoning using behenic acid (C22) as a feedstock was its high phosphorus content. The decarboxylation rate of fatty acids decreased also with increasing fatty acid to metal ratio.
Alkuperäiskieli | Englanti |
---|---|
Sivut | 28-31 |
Sivumäärä | 4 |
Julkaisu | Catalysis Today |
Vuosikerta | 150 |
Numero | 1-2 |
DOI - pysyväislinkit | |
Tila | Julkaistu - 26 helmik. 2010 |
OKM-julkaisutyyppi | A1 Julkaistu artikkeli, soviteltu |