TY - JOUR
T1 - Composite of methyl polysiloxane and avocado biochar as adsorbent for removal of ciprofloxacin from waters
AU - Teixeira, Roberta A.
AU - Lima, Eder C.
AU - Benetti, Antônio D.
AU - Thue, Pascal S.
AU - Lima, Diana R.
AU - Sher, Farooq
AU - dos Reis, Glaydson S.
AU - Rabiee, Navid
AU - Seliem, Moaaz K.
AU - Abatal, Mohamed
N1 - Publisher Copyright:
© 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
PY - 2022/10
Y1 - 2022/10
N2 - Two carbon composite materials were prepared by mixing avocado biochar and methyl polysiloxane (MK). Firstly, MK was dissolved in ethanol, and then the biochar was added at different times. In sample 1 (R1), the time of adding biochar was immediately after dissolving MK in ethanol, and in sample 2 (R2), after 48 h of MK dissolved in ethanol. The samples were characterized by nitrogen adsorption/desorption measurements obtaining specific surface areas (SBET) of 115 m2 g−1 (R1) and 580 m2 g−1 (R2). The adsorbents were further characterized using scanning electron microscopy, FTIR and Raman spectroscopy, adsorption of vapors of n-heptane and water, thermal analysis, Bohem titration, pHpzc, and C H N elemental analysis. R1 and R2 adsorbents were employed as adsorbents to remove the antibiotic ciprofloxacin from the waters. The t1/2 and t0.95 based on the interpolation of Avrami fractional-order were 20.52 and 246.4 min (R1) and 14.00 and 157.6 min (R2), respectively. Maximum adsorption capacities (Qmax) based on the Liu isotherm were 10.77 (R1) and 63.80 mg g−1 (R2) for ciprofloxacin. The thermodynamic studies showed a spontaneous and exothermic process for both samples, and the value of ΔH° is compatible with physical adsorption.
AB - Two carbon composite materials were prepared by mixing avocado biochar and methyl polysiloxane (MK). Firstly, MK was dissolved in ethanol, and then the biochar was added at different times. In sample 1 (R1), the time of adding biochar was immediately after dissolving MK in ethanol, and in sample 2 (R2), after 48 h of MK dissolved in ethanol. The samples were characterized by nitrogen adsorption/desorption measurements obtaining specific surface areas (SBET) of 115 m2 g−1 (R1) and 580 m2 g−1 (R2). The adsorbents were further characterized using scanning electron microscopy, FTIR and Raman spectroscopy, adsorption of vapors of n-heptane and water, thermal analysis, Bohem titration, pHpzc, and C H N elemental analysis. R1 and R2 adsorbents were employed as adsorbents to remove the antibiotic ciprofloxacin from the waters. The t1/2 and t0.95 based on the interpolation of Avrami fractional-order were 20.52 and 246.4 min (R1) and 14.00 and 157.6 min (R2), respectively. Maximum adsorption capacities (Qmax) based on the Liu isotherm were 10.77 (R1) and 63.80 mg g−1 (R2) for ciprofloxacin. The thermodynamic studies showed a spontaneous and exothermic process for both samples, and the value of ΔH° is compatible with physical adsorption.
KW - Adsorption thermodynamics
KW - Hydrophobic surface
KW - Methyl polysiloxane and biochar composite
KW - Pharmaceutical adsorption
KW - Synthetic effluents
UR - http://www.scopus.com/inward/record.url?scp=85131059596&partnerID=8YFLogxK
U2 - 10.1007/S11356-022-21176-Z
DO - 10.1007/S11356-022-21176-Z
M3 - Article
C2 - 35641743
SN - 0944-1344
VL - 29
SP - 74823
EP - 74840
JO - Environmental Science and Pollution Research
JF - Environmental Science and Pollution Research
IS - 49
ER -