@article{f37315a5db08418ea12d4ad95a628f6b,
title = "Chemo-bio catalyzed synthesis of R-1-phenylethyl acetate over bimetallic PdZn catalysts, lipase, and Ru/Al2O3. Part II",
abstract = "One-pot synthesis of R-1-phenyethylacetate at 70°C was investigated using three different catalysts simultaneously, namely a bimetallic PdZn/Al 2O3 as a hydrogenation catalyst, an immobilized lipase as an acylation catalyst and Ru/Al2O3 as a racemization catalyst. The most active bimetallic catalyst was PdZn/Al2O 3 calcined at 300°C and reduced at 400°C, whereas the most selective although less active catalyst was the one being calcined and reduced at 500°C. The highest selectivity to R-1-phenylethyl acetate over this catalyst was 32 at 48% conversion. Ru/Al2O3 was confirmed to have a positive effect on the formation of the desired product, although it was not very active in the racemization during one-pot synthesis.",
author = "A. Kirilin and P. M{\"a}ki-Arvela and K. Kordas and A.-R. Leino and A. Shchukarev and D. Bostr{\"o}m and J.-P. Mikkola and Kustov, {L. M.} and Salmi, {T. O.} and Murzin, {D. Yu}",
note = "Funding Information: ACKNOWLEDGMENTS This work is part of the activities at the {\AA}bo Aka demi Process Chemistry Centre ({\AA}A PCC) within the Finnish Centre of Excellence Programme (2000– 2011) appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grants 120853, 124357, and 128626. This work is also associated with the activities of Ume{\aa} University Chemical Biological Centre whereupon financial support from Ume{\aa} Uni versity, Kempe foundation and Markus Wallenberg foundation are acknowledged. Copyright: Copyright 2011 Elsevier B.V., All rights reserved.",
year = "2011",
month = feb,
doi = "10.1134/S0023158411010095",
language = "English",
volume = "52",
pages = "77--81",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "Springer",
}