Aqueous-phase reforming of xylitol over Pt/C and Pt/TiC-CDC catalysts: catalyst characterization and catalytic performance

Alexey Kirilin, Benjamin Hasse, Anton Tokarev, Leonid M. Kustov, Galina N. Baeva, Galina O. Bragina, Aleksandr Yu. Stakheev, Anne-Riikka Rautio, Tapio Salmi, Bastian J. M. Etzold, Jyri-Pekka Mikkola, Dmitry Murzin

    Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

    40 Sitaatiot (Scopus)

    Abstrakti

    The aqueous phase reforming (APR) of xylitol was studied over five Pt/C catalysts. The correlation between physico-chemical properties of the catalysts and catalytic performance was established. The Pt/C catalysts have different textural properties as well as different mean Pt cluster sizes and surface acidity. The average Pt cluster size was investigated by means of CO chemisorption as well as by TEM. The reaction was found to be structure sensitive and TOF linearly increases with increasing average Pt cluster size in the studied domain. The catalysts which possess higher surface acidity favoured higher rates of hydrocarbon production. On the contrary the Pt/C materials with lower acidities generated hydrogen with high selectivity and TOF.
    AlkuperäiskieliEi tiedossa
    Sivut387–401
    JulkaisuCatalysis Science and Technology
    Vuosikerta4
    Numero2
    DOI - pysyväislinkit
    TilaJulkaistu - 2014
    OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

    Viittausmuodot