A short semi-synthesis and complete NMR-spectroscopic characterization of the naturally occurring lignan glycoside matairesinol 4,4 '-di-O-beta-D-diglucoside

    Tutkimustuotos: LehtiartikkeliArtikkeliTieteellinenvertaisarvioitu

    5 Sitaatiot (Scopus)

    Abstrakti

    A convenient semi-synthesis of (8R,8'R)-matairesinol 4,4'-di-O-beta-D-glucopyranoside (MDG), found in the stems of Trachelospermum asiaticum var. intermedium, is described starting from the readily available starting materials D-glucose and hydroxymatairesinol. By this approach the synthesis of MDG can be accomplished in six steps with an overall yield of 28%. In addition, the first complete NMR-spectroscopic characterization of MDG was accomplished by the combination of standard NMR techniques and spectral simulations performed with the PERCH NMR simulation software. (C) 2010 Elsevier Ltd. All rights reserved.
    AlkuperäiskieliEi tiedossa
    Sivut1963–1967
    Sivumäärä5
    JulkaisuCarbohydrate Research
    Vuosikerta345
    Numero13
    DOI - pysyväislinkit
    TilaJulkaistu - 2010
    OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

    Keywords

    • Lignan glycoside
    • NMR spectroscopy
    • Semi-synthesis
    • Trachelospermum asiaticum var. intermedium

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