Ultrasonic irradiation in enantioselective hydrogenation of 1-phenyl-1,2-propanedione

Esa Toukoniitty; Päivi Mäki-Arvela; Ahmad Kalantar Neyestanaki; Ensio Laine; Jyri Pekka Mikkola; Tapio Salmi; Dmitry Yu Murzin

doi:10.1023/A:1013961631220

Ultrasonic irradiation in enantioselective hydrogenation of 1-phenyl-1,2-propanedione

Esa Toukoniitty^*
, Päivi Mäki-Arvela
, Ahmad Kalantar Neyestanaki
, Ensio Laine
, Jyri Pekka Mikkola
, Tapio Salmi
, Dmitry Yu Murzin

^*Corresponding author for this work

Laboratory of Industrial Chemistry and Reaction Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

8 Citations (Scopus)

Abstract

In the presence of ultrasound both the initial hydrogenation rate of 1-phenyl-1,2-propanedione and the enantiomeric excess of the main product, i.e. (R)-1-hydroxy-1-phenylpropanone, increased by 75 % and 52 % in toluene, respectively, as compared to the silent hydrogenation.

Original language	English
Pages (from-to)	3-11
Number of pages	9
Journal	Reaction Kinetics and Catalysis Letters
Volume	73
Issue number	1
DOIs	https://doi.org/10.1023/A:1013961631220
Publication status	Published - 2001
MoE publication type	A1 Journal article-refereed

Funding

of Inorganic Chemistry, Åbo Akademi University) for the SEM micrographs. Financial support for this work was obtained from Academy of Finland.

Keywords

Dione
Enantioselective hydrogenation
Ultrasound

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10.1023/A:1013961631220

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title = "Ultrasonic irradiation in enantioselective hydrogenation of 1-phenyl-1,2-propanedione",

abstract = "In the presence of ultrasound both the initial hydrogenation rate of 1-phenyl-1,2-propanedione and the enantiomeric excess of the main product, i.e. (R)-1-hydroxy-1-phenylpropanone, increased by 75 \% and 52 \% in toluene, respectively, as compared to the silent hydrogenation.",

keywords = "Dione, Enantioselective hydrogenation, Ultrasound",

author = "Esa Toukoniitty and P{\"a}ivi M{\"a}ki-Arvela and \{Kalantar Neyestanaki\}, Ahmad and Ensio Laine and Mikkola, \{Jyri Pekka\} and Tapio Salmi and Murzin, \{Dmitry Yu\}",

note = "Funding Information: of Inorganic Chemistry, {\AA}bo Akademi University) for the SEM micrographs. Financial support for this work was obtained from Academy of Finland. Copyright: Copyright 2005 Elsevier Science B.V., Amsterdam. All rights reserved.",

year = "2001",

doi = "10.1023/A:1013961631220",

language = "English",

volume = "73",

pages = "3--11",

journal = "Reaction Kinetics and Catalysis Letters",

issn = "0133-1736",

publisher = "Springer",

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TY - JOUR

T1 - Ultrasonic irradiation in enantioselective hydrogenation of 1-phenyl-1,2-propanedione

AU - Toukoniitty, Esa

AU - Mäki-Arvela, Päivi

AU - Kalantar Neyestanaki, Ahmad

AU - Laine, Ensio

AU - Mikkola, Jyri Pekka

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

N1 - Funding Information: of Inorganic Chemistry, Åbo Akademi University) for the SEM micrographs. Financial support for this work was obtained from Academy of Finland. Copyright: Copyright 2005 Elsevier Science B.V., Amsterdam. All rights reserved.

PY - 2001

Y1 - 2001

N2 - In the presence of ultrasound both the initial hydrogenation rate of 1-phenyl-1,2-propanedione and the enantiomeric excess of the main product, i.e. (R)-1-hydroxy-1-phenylpropanone, increased by 75 % and 52 % in toluene, respectively, as compared to the silent hydrogenation.

AB - In the presence of ultrasound both the initial hydrogenation rate of 1-phenyl-1,2-propanedione and the enantiomeric excess of the main product, i.e. (R)-1-hydroxy-1-phenylpropanone, increased by 75 % and 52 % in toluene, respectively, as compared to the silent hydrogenation.

KW - Dione

KW - Enantioselective hydrogenation

KW - Ultrasound

UR - https://www.scopus.com/pages/publications/18044403749

U2 - 10.1023/A:1013961631220

DO - 10.1023/A:1013961631220

M3 - Article

AN - SCOPUS:18044403749

SN - 0133-1736

VL - 73

SP - 3

EP - 11

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 1

ER -

Ultrasonic irradiation in enantioselective hydrogenation of 1-phenyl-1,2-propanedione

Abstract

Funding

Keywords

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