Thermodynamic Properties of Magnetic Semiconductors Ag2FeSn3S8 and Ag2FeSnS4 Determined by the EMF Method

Mykola Moroz; Fiseha Tesfaye; Pavlo Demchenko; Myroslava Prokhorenko; Daniel Lindberg; Oleksandr Reshetnyak; Leena Hupa

doi:10.1007/978-3-319-72131-6_8

Thermodynamic Properties of Magnetic Semiconductors Ag2FeSn3S8 and Ag2FeSnS4 Determined by the EMF Method

Mykola Moroz, Fiseha Tesfaye, Pavlo Demchenko, Myroslava Prokhorenko, Daniel Lindberg, Oleksandr Reshetnyak, Leena Hupa

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

6 Citations (Scopus)

Abstract

Phase equilibria andthermodynamics in the Ag₂SnS₃–SnS–Sn₂S₃–FeSsystem were investigated using differential thermal analysis, X-raydiffraction, and EMF methods. Determined phase relations were used to expressthe forming chemical reactions for compounds Ag₂FeSn₃S₈and Ag₂FeSnS₄. The forming chemical reactions wereperformed by applying electrochemical cells of the types:(–) C | Ag | Ag₃GeS₃I glass |Ag₂FeSn₃S₈, SnS, Sn₂S₃,FeS | C (+) and (–) C | Ag | Ag₃GeS₃I glass |Ag₂FeSnS₄, SnS, Ag₂FeSn₃S₈,FeS | C (+). Based on the measured EMF vs. temperaturerelations, experimental thermodynamic data of the quaternary phases Ag₂FeSn₃S₈and Ag₂FeSnS₄ were derived for the first time.

Original language	Undefined/Unknown
Title of host publication	Materials Processing Fundamentals 2018. TMS 2018
Editors	G. Lambotte, J. Lee, A. Allanore, S. Wagstaff
Publisher	Springer
Pages	87–98
ISBN (Electronic)	978-3-319-72131-6
ISBN (Print)	978-3-319-72130-9
DOIs	https://doi.org/10.1007/978-3-319-72131-6_8
Publication status	Published - 2018
MoE publication type	A3 Part of a book or another research book

Keywords

EMF method
Magnetic semiconductors
Thermodynamic properties

Access to Document

10.1007/978-3-319-72131-6_8

https://link.springer.com/chapter/10.1007/978-3-319-72131-6_8

Cite this

Moroz, M., Tesfaye, F., Demchenko, P., Prokhorenko, M., Lindberg, D., Reshetnyak, O., & Hupa, L. (2018). Thermodynamic Properties of Magnetic Semiconductors Ag2FeSn3S8 and Ag2FeSnS4 Determined by the EMF Method. In G. Lambotte, J. Lee, A. Allanore, & S. Wagstaff (Eds.), Materials Processing Fundamentals 2018. TMS 2018 (pp. 87–98). Springer. https://doi.org/10.1007/978-3-319-72131-6_8

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title = "Thermodynamic Properties of Magnetic Semiconductors Ag2FeSn3S8 and Ag2FeSnS4 Determined by the EMF Method",

abstract = "Phase equilibria andthermodynamics in the Ag2SnS3–SnS–Sn2S3–FeSsystem were investigated using differential thermal analysis, X-raydiffraction, and EMF methods. Determined phase relations were used to expressthe forming chemical reactions for compounds Ag2FeSn3S8and Ag2FeSnS4. The forming chemical reactions wereperformed by applying electrochemical cells of the types:(–) C | Ag | Ag3GeS3I glass |Ag2FeSn3S8, SnS, Sn2S3,FeS | C (+) and (–) C | Ag | Ag3GeS3I glass |Ag2FeSnS4, SnS, Ag2FeSn3S8,FeS | C (+). Based on the measured EMF vs. temperaturerelations, experimental thermodynamic data of the quaternary phases Ag2FeSn3S8and Ag2FeSnS4 were derived for the first time.",

keywords = "EMF method, Magnetic semiconductors, Thermodynamic properties, EMF method, Magnetic semiconductors, Thermodynamic properties, EMF method, Magnetic semiconductors, Thermodynamic properties",

author = "Mykola Moroz and Fiseha Tesfaye and Pavlo Demchenko and Myroslava Prokhorenko and Daniel Lindberg and Oleksandr Reshetnyak and Leena Hupa",

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Moroz, M, Tesfaye, F, Demchenko, P, Prokhorenko, M, Lindberg, D, Reshetnyak, O & Hupa, L 2018, Thermodynamic Properties of Magnetic Semiconductors Ag2FeSn3S8 and Ag2FeSnS4 Determined by the EMF Method. in G Lambotte, J Lee, A Allanore & S Wagstaff (eds), Materials Processing Fundamentals 2018. TMS 2018. Springer, pp. 87–98. https://doi.org/10.1007/978-3-319-72131-6_8

Thermodynamic Properties of Magnetic Semiconductors Ag2FeSn3S8 and Ag2FeSnS4 Determined by the EMF Method. / Moroz, Mykola; Tesfaye, Fiseha; Demchenko, Pavlo et al.
Materials Processing Fundamentals 2018. TMS 2018. ed. / G. Lambotte; J. Lee; A. Allanore; S. Wagstaff. Springer, 2018. p. 87–98.

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

TY - CHAP

T1 - Thermodynamic Properties of Magnetic Semiconductors Ag2FeSn3S8 and Ag2FeSnS4 Determined by the EMF Method

AU - Moroz, Mykola

AU - Tesfaye, Fiseha

AU - Demchenko, Pavlo

AU - Prokhorenko, Myroslava

AU - Lindberg, Daniel

AU - Reshetnyak, Oleksandr

AU - Hupa, Leena

N1 - OOK

PY - 2018

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N2 - Phase equilibria andthermodynamics in the Ag2SnS3–SnS–Sn2S3–FeSsystem were investigated using differential thermal analysis, X-raydiffraction, and EMF methods. Determined phase relations were used to expressthe forming chemical reactions for compounds Ag2FeSn3S8and Ag2FeSnS4. The forming chemical reactions wereperformed by applying electrochemical cells of the types:(–) C | Ag | Ag3GeS3I glass |Ag2FeSn3S8, SnS, Sn2S3,FeS | C (+) and (–) C | Ag | Ag3GeS3I glass |Ag2FeSnS4, SnS, Ag2FeSn3S8,FeS | C (+). Based on the measured EMF vs. temperaturerelations, experimental thermodynamic data of the quaternary phases Ag2FeSn3S8and Ag2FeSnS4 were derived for the first time.

AB - Phase equilibria andthermodynamics in the Ag2SnS3–SnS–Sn2S3–FeSsystem were investigated using differential thermal analysis, X-raydiffraction, and EMF methods. Determined phase relations were used to expressthe forming chemical reactions for compounds Ag2FeSn3S8and Ag2FeSnS4. The forming chemical reactions wereperformed by applying electrochemical cells of the types:(–) C | Ag | Ag3GeS3I glass |Ag2FeSn3S8, SnS, Sn2S3,FeS | C (+) and (–) C | Ag | Ag3GeS3I glass |Ag2FeSnS4, SnS, Ag2FeSn3S8,FeS | C (+). Based on the measured EMF vs. temperaturerelations, experimental thermodynamic data of the quaternary phases Ag2FeSn3S8and Ag2FeSnS4 were derived for the first time.

KW - EMF method

KW - Magnetic semiconductors

KW - Thermodynamic properties

KW - EMF method

KW - Magnetic semiconductors

KW - Thermodynamic properties

KW - EMF method

KW - Magnetic semiconductors

KW - Thermodynamic properties

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DO - 10.1007/978-3-319-72131-6_8

M3 - Kapitel

SN - 978-3-319-72130-9

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EP - 98

BT - Materials Processing Fundamentals 2018. TMS 2018

A2 - Lambotte, G.

A2 - Lee, J.

A2 - Allanore, A.

A2 - Wagstaff, S.

PB - Springer

ER -