The kinetics of simultaneous aqueous extraction and hydrolysis of spruce hemicelluloses

Jussi Rissanen, Henrik Grénman*, Chunlin Xu, Jens Krogell, Stefan Willför, Dmitry Murzin, Tapio Salmi

*Corresponding author for this work

Research output: Contribution to conferencePaper (not published)peer-review

Abstract

The aqueous extraction of hemicelluloses has gained an increasing interest with new emerging applications for hemicelluloses in the modern forest-based biorefinery concept. The extraction kinetics play a key role in their industrial utilisation. Pressurised hot water extraction of spruce sap wood was investigated in the temperature range 120–170°C using a large liquid-to-solid ratio in an intensified cascade reactor system. The results show significant temperature dependence of the extraction rate, albeit low influence of pH. Moreover, a clear dependence of the hydrolysis rate on the temperature and pH was observed. The molecular mass of the extracted hemicelluloses was influenced by the chip size. A kinetic model was developed for describing the extraction kinetics.

Original languageEnglish
Pages416-417
Number of pages2
Publication statusPublished - 2012
MoE publication typeO2 Other
Event4th Nordic Wood Biorefinery Conference, NWBC 2012 - Helsinki, Finland
Duration: 23 Oct 201225 Oct 2012

Conference

Conference4th Nordic Wood Biorefinery Conference, NWBC 2012
Country/TerritoryFinland
CityHelsinki
Period23/10/1225/10/12

Funding

This research was part of the activities at the Åbo Akademi Process Chemistry Centre. This study was financed by Forestcluster Ltd. and the Finnish Funding Agency for Technology and Innovation (Tekes) within the framework of the Future Biorefinery (FuBio) Joint Research 2 programme.

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