The impinging jet flow cell - a novel method for the study of PEM fuel cell material

U Koponen; T Peltonen; Mikael Bergelin; T Mennola; M Valkiainen; J Kaskimies; Mikael Wasberg

doi:10.1016/S0378-7753(99)00497-8

The impinging jet flow cell - a novel method for the study of PEM fuel cell material

U Koponen, T Peltonen, Mikael Bergelin, T Mennola, M Valkiainen, J Kaskimies, Mikael Wasberg

Research output: Contribution to journal › Article › Scientific › peer-review

20 Citations (Scopus)

Abstract

The electrocatalytic properties of a fuel cell catalyst ink in thin film form based on Vulcan XC72/Pt (30%) and Nafion was investigated by means of a flow cell of impinging jet type in flows of H2 and H2+CO dissolved in H2SO4 electrolyte. CO ad layers of different coverages were produced by a dosing procedure and their electrooxidative removal was studied. Ru was deposited onto the ink in situ by electroredn. and the basic voltammetry of such electrodes was investigated as well as the influence on CO ad layers and CO-tolerance. A Nafion film on top of the ink film influenced both the behavior of CO ad layers and CO-tolerance. The feasibility of the flow cell for investigation and modification of ink electrodes were demonstrated.

Original language	Undefined/Unknown
Pages (from-to)	261–268
Journal	Journal of Power Sources
Volume	86
Issue number	1-2
DOIs	https://doi.org/10.1016/S0378-7753(99)00497-8
Publication status	Published - 2000
MoE publication type	A1 Journal article-refereed

Access to Document

10.1016/S0378-7753(99)00497-8

Cite this

@article{e88fe6f8cd164d019a125a9627712668,

title = "The impinging jet flow cell - a novel method for the study of PEM fuel cell material",

abstract = "The electrocatalytic properties of a fuel cell catalyst ink in thin film form based on Vulcan XC72/Pt (30%) and Nafion was investigated by means of a flow cell of impinging jet type in flows of H2 and H2+CO dissolved in H2SO4 electrolyte. CO ad layers of different coverages were produced by a dosing procedure and their electrooxidative removal was studied. Ru was deposited onto the ink in situ by electroredn. and the basic voltammetry of such electrodes was investigated as well as the influence on CO ad layers and CO-tolerance. A Nafion film on top of the ink film influenced both the behavior of CO ad layers and CO-tolerance. The feasibility of the flow cell for investigation and modification of ink electrodes were demonstrated.",

author = "U Koponen and T Peltonen and Mikael Bergelin and T Mennola and M Valkiainen and J Kaskimies and Mikael Wasberg",

year = "2000",

doi = "10.1016/S0378-7753(99)00497-8",

language = "Odefinierat/ok{\"a}nt",

volume = "86",

pages = "261–268",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - The impinging jet flow cell - a novel method for the study of PEM fuel cell material

AU - Koponen, U

AU - Peltonen, T

AU - Bergelin, Mikael

AU - Mennola, T

AU - Valkiainen, M

AU - Kaskimies, J

AU - Wasberg, Mikael

PY - 2000

Y1 - 2000

N2 - The electrocatalytic properties of a fuel cell catalyst ink in thin film form based on Vulcan XC72/Pt (30%) and Nafion was investigated by means of a flow cell of impinging jet type in flows of H2 and H2+CO dissolved in H2SO4 electrolyte. CO ad layers of different coverages were produced by a dosing procedure and their electrooxidative removal was studied. Ru was deposited onto the ink in situ by electroredn. and the basic voltammetry of such electrodes was investigated as well as the influence on CO ad layers and CO-tolerance. A Nafion film on top of the ink film influenced both the behavior of CO ad layers and CO-tolerance. The feasibility of the flow cell for investigation and modification of ink electrodes were demonstrated.

AB - The electrocatalytic properties of a fuel cell catalyst ink in thin film form based on Vulcan XC72/Pt (30%) and Nafion was investigated by means of a flow cell of impinging jet type in flows of H2 and H2+CO dissolved in H2SO4 electrolyte. CO ad layers of different coverages were produced by a dosing procedure and their electrooxidative removal was studied. Ru was deposited onto the ink in situ by electroredn. and the basic voltammetry of such electrodes was investigated as well as the influence on CO ad layers and CO-tolerance. A Nafion film on top of the ink film influenced both the behavior of CO ad layers and CO-tolerance. The feasibility of the flow cell for investigation and modification of ink electrodes were demonstrated.

U2 - 10.1016/S0378-7753(99)00497-8

DO - 10.1016/S0378-7753(99)00497-8

M3 - Artikel

SN - 0378-7753

VL - 86

SP - 261

EP - 268

JO - Journal of Power Sources

JF - Journal of Power Sources

IS - 1-2

ER -