The development of the method of low-temperature peat pyrolysis on the basis of alumosilicate catalytic system

E. M. Sulman; V. V. Alferov; Yu Yu Kosivtsov; A. I. Sidorov; O. S. Misnikov; A. E. Afanasiev; N. Kumar; D. Kubicka; J. Agullo; T. Salmi; D. Yu Murzin

doi:10.1016/j.cej.2007.03.071

The development of the method of low-temperature peat pyrolysis on the basis of alumosilicate catalytic system

E. M. Sulman^*, V. V. Alferov, Yu Yu Kosivtsov, A. I. Sidorov, O. S. Misnikov, A. E. Afanasiev, N. Kumar, D. Kubicka, J. Agullo, T. Salmi, D. Yu Murzin

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

26 Citations (Scopus)

Abstract

The catalytic pyrolysis of peat was investigated over several iron-containing zeolites of different structure (Beta, Y, Mordenite, ZSM-5) and SiO₂/Al₂O₃ molar ratios at 410 °C in a batch mode. The overall activity of iron-containing catalysts was similar, being however significantly higher than activity of parent materials. Additionally, iron-modified zeolites afforded higher ethene and propene selectivity than corresponding proton forms.

Original language	English
Pages (from-to)	162-167
Number of pages	6
Journal	Chemical Engineering Journal
Volume	134
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cej.2007.03.071
Publication status	Published - 1 Nov 2007
MoE publication type	A1 Journal article-refereed

Funding

This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programs (2000–2011) by the Academy of Finland. International Marie-Curie Fellowship by European Commission to Javier Agullo Pastor is greatfully acknowledged.

Keywords

Biomass
Pyrolysis
Zeolites

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10.1016/j.cej.2007.03.071

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Sulman, E. M., Alferov, V. V., Kosivtsov, Y. Y., Sidorov, A. I., Misnikov, O. S., Afanasiev, A. E., Kumar, N., Kubicka, D., Agullo, J., Salmi, T., & Murzin, D. Y. (2007). The development of the method of low-temperature peat pyrolysis on the basis of alumosilicate catalytic system. Chemical Engineering Journal, 134(1-3), 162-167. https://doi.org/10.1016/j.cej.2007.03.071

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title = "The development of the method of low-temperature peat pyrolysis on the basis of alumosilicate catalytic system",

abstract = "The catalytic pyrolysis of peat was investigated over several iron-containing zeolites of different structure (Beta, Y, Mordenite, ZSM-5) and SiO2/Al2O3 molar ratios at 410 °C in a batch mode. The overall activity of iron-containing catalysts was similar, being however significantly higher than activity of parent materials. Additionally, iron-modified zeolites afforded higher ethene and propene selectivity than corresponding proton forms.",

keywords = "Biomass, Pyrolysis, Zeolites",

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note = "Funding Information: This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programs (2000–2011) by the Academy of Finland. International Marie-Curie Fellowship by European Commission to Javier Agullo Pastor is greatfully acknowledged. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2007",

month = nov,

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doi = "10.1016/j.cej.2007.03.071",

language = "English",

volume = "134",

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T1 - The development of the method of low-temperature peat pyrolysis on the basis of alumosilicate catalytic system

AU - Sulman, E. M.

AU - Alferov, V. V.

AU - Kosivtsov, Yu Yu

AU - Sidorov, A. I.

AU - Misnikov, O. S.

AU - Afanasiev, A. E.

AU - Kumar, N.

AU - Kubicka, D.

AU - Agullo, J.

AU - Salmi, T.

AU - Murzin, D. Yu

N1 - Funding Information: This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programs (2000–2011) by the Academy of Finland. International Marie-Curie Fellowship by European Commission to Javier Agullo Pastor is greatfully acknowledged. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2007/11/1

Y1 - 2007/11/1

N2 - The catalytic pyrolysis of peat was investigated over several iron-containing zeolites of different structure (Beta, Y, Mordenite, ZSM-5) and SiO2/Al2O3 molar ratios at 410 °C in a batch mode. The overall activity of iron-containing catalysts was similar, being however significantly higher than activity of parent materials. Additionally, iron-modified zeolites afforded higher ethene and propene selectivity than corresponding proton forms.

AB - The catalytic pyrolysis of peat was investigated over several iron-containing zeolites of different structure (Beta, Y, Mordenite, ZSM-5) and SiO2/Al2O3 molar ratios at 410 °C in a batch mode. The overall activity of iron-containing catalysts was similar, being however significantly higher than activity of parent materials. Additionally, iron-modified zeolites afforded higher ethene and propene selectivity than corresponding proton forms.

KW - Biomass

KW - Pyrolysis

KW - Zeolites

UR - https://www.scopus.com/pages/publications/34548238713

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DO - 10.1016/j.cej.2007.03.071

M3 - Article

AN - SCOPUS:34548238713

SN - 1385-8947

VL - 134

SP - 162

EP - 167

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

IS - 1-3

ER -

The development of the method of low-temperature peat pyrolysis on the basis of alumosilicate catalytic system

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