Synthesis of dimethyl carbonate from methanol and carbon dioxide the effect of dehydration

V. Eta*, P. Mäki-Arvela, D. Y. Murzin, T. Salmi, J. P. Mikkola

*Corresponding author for this work

Research output: Contribution to conferencePaper (not published)peer-review

Abstract

The catalytic activity of zirconia in the synthesis of dimethyl carbonate (DMC) from methanol and CO2 was studied. The thermodynamic properties of the reaction were estimated at different temperatures and pressures. Kinetic tests were carried out to determine the maximum yield and selectivity for DMC at different conditions. The limitations imposed by thermodynamics could be relaxed by using a chemical water trap to bind water produced during the reaction between methanol and CO2 thereby shifting the reaction equilibrium towards higher DMC yields. The catalytic performance improved significantly in the presence of strong basic sites incorporated into zirconia. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montreal, Quebec, Canada 8/23-27/2009).

Original languageEnglish
Pages522bc
Publication statusPublished - 2009
MoE publication typeO2 Other
Event8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering - Montreal, QC, Canada
Duration: 23 Aug 200927 Aug 2009

Conference

Conference8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
CountryCanada
CityMontreal, QC
Period23/08/0927/08/09

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