Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin

Yury Brusentsev; Patrik Christoffer Eklund

doi:10.1055/s-0035-1562605

Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin

Yury Brusentsev, Patrik Christoffer Eklund

Research output: Contribution to journal › Article › Scientific › peer-review

2 Citations (Scopus)

Abstract

Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.

Original language	Undefined/Unknown
Pages (from-to)	2557–2560
Journal	Synlett
Volume	27
Issue number	18
DOIs	https://doi.org/10.1055/s-0035-1562605
Publication status	Published - 2016
MoE publication type	A1 Journal article-refereed

Keywords

chiral phosphites
chiral phosphates
conidendrin
Lignan
matairesinol
chiral pool
chiral 1,4-diols

Access to Document

10.1055/s-0035-1562605

http://www.thieme-connect.de/DOI/DOI?10.1055/s-0035-1562605

Cite this

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title = "Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin",

abstract = "Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.",

keywords = "chiral phosphites, chiral phosphates, conidendrin, Lignan, matairesinol, chiral pool, chiral 1,4-diols, chiral phosphites, chiral phosphates, conidendrin, Lignan, matairesinol, chiral pool, chiral 1,4-diols, chiral phosphites, chiral phosphates, conidendrin, Lignan, matairesinol, chiral pool, chiral 1,4-diols",

author = "Yury Brusentsev and Eklund, {Patrik Christoffer}",

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year = "2016",

doi = "10.1055/s-0035-1562605",

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T1 - Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin

AU - Brusentsev, Yury

AU - Eklund, Patrik Christoffer

N1 - iok

PY - 2016

Y1 - 2016

N2 - Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.

AB - Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.

KW - chiral phosphites

KW - chiral phosphates

KW - conidendrin

KW - Lignan

KW - matairesinol

KW - chiral pool

KW - chiral 1,4-diols

KW - chiral phosphites

KW - chiral phosphates

KW - conidendrin

KW - Lignan

KW - matairesinol

KW - chiral pool

KW - chiral 1,4-diols

KW - chiral phosphites

KW - chiral phosphates

KW - conidendrin

KW - Lignan

KW - matairesinol

KW - chiral pool

KW - chiral 1,4-diols

U2 - 10.1055/s-0035-1562605

DO - 10.1055/s-0035-1562605

M3 - Artikel

SN - 0936-5214

VL - 27

SP - 2557

EP - 2560

JO - Synlett

JF - Synlett

IS - 18

ER -