Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin

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Abstract

Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.
Original languageUndefined/Unknown
Pages (from-to)2557–2560
JournalSynlett
Volume27
Issue number18
DOIs
Publication statusPublished - 2016
MoE publication typeA1 Journal article-refereed

Keywords

  • chiral phosphites
  • chiral phosphates
  • conidendrin
  • Lignan
  • matairesinol
  • chiral pool
  • chiral 1,4-diols

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